| 1210820-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1210820-77-1
• 化学式: C₂₄H₂₂N₄O
• 分子量: 382.465
• InChiKey: SMXSUQDEZKJOON-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 三乙胺 作用下， 以 甲醇 为溶剂， 反应 0.5h， 生成 3-甲基-5-苯基-1H-1,2,4-三唑 、 4,6-Dimethylbenzo[f]quinolin-3-one 、
  参考文献：
  名称：

  Substituent Effects on the Electron Transfer-Initiated Photochemical Transformation of 1,2,4-Triazole-Substituted α-Dehydroarylalaninamides into 2(1H)-Quinolinone Derivatives

  摘要：

  An investigation was undertaken to elucidate substituent effects on the photoreactivity of 1,2,4-triazole-substituted alpha-dehydroarylalaninamides [(Z)-1] as well as on the selectivity of 2(1H)-quinolinone derivatives (2) from a synthetic point of view. It was found that photoinduced electron transfer-initiated cyclization of (Z)-1 bearing a meta-substituted phenyl or a 4-substituted naphthalen-1-yl group in methanol proceeds with a moderate to good efficiency affording the corresponding product 2 in a selectivity ranging from 33 to 100%.

  DOI：

  10.3987/com-09-s(s)55