[Cu(acetylacetonate)(phen)(H₂O)](ClO₄) | 639458-11-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Cu(acetylacetonate)(phen)(H₂O)](ClO₄)
• 英文别名: [Cu(acetylacetonate)(1,10-phenanthroline)(H₂O)](ClO₄)；[Cu(acetylacetonato)(1,10-phenanthroline)(H2O)](ClO4)；[Cu(acac)(phen)(H2O)](ClO4)；[copper(II)(acetylacetonato)(1,10-phenantroline)(water)]ClO4
• CAS: 639458-11-0
• 化学式: C₁₇H₁₇CuN₂O₃*ClO₄
• 分子量: 460.33
• InChiKey: NMQIEDIACZMHCV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(acetylacetonate)(phen)(H₂O)](ClO₄) 、 Ni(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate)) 以 甲醇 、 乙腈 为溶剂， 生成 [Cu(acetylacetonato)(1,10-phenanthroline)(H2O)][Ni((CH2NCHC6H3(OCH3)O)2)](ClO4)
  参考文献：
  名称：

  Metal complexes as second-sphere ligands

  摘要：

  由单核方形平面镍（II）或钯（II）络合物构建的新型超级络合物是铜络合物中水配体的宿主受体。

  DOI：

  10.1039/b517989k

文献信息

• Supramolecular Bimetallic Systems Constructed through π‐π Stacking and Hydrogen Bond Interactions
  作者：Augustin M. Madalan、Marius Andruh、Narcis Avarvari、Marc Fourmigué

  DOI：10.1080/15533170701740834

  日期：2007.12.1

  (5) (Me2bipy=4,4′‐dimethyl‐2,2′‐bipyridine; mnt=maleonitriledithiolate). The molecular structures of complexes 1 and 2 are similar: they consist of neutral [Cu(acac)(BB)}2Ni(CN)4}] entities, which result by connecting two [Cu(acac)(BB)]+ ions through two trans‐cyano groups from the bridging ligand, [Ni(CN)4]2− (BB=1,10‐phenanthroline and, respectively, 2,2′‐bipyridine). The intermolecular π‐π stacking

  已经合成了五种新的双金属化合物并对其进行了晶体学表征：[Cu(acac)(phen)}2Ni(CN)4}]·H2O (1), [Cu(acac)(bipy)}2Ni( CN)4}] (2); [Cu(acac)(bipy)( )]2[Ni(CN)4] (3), [(Cu(acac)(Me2bipy)]2[Ni(mnt)2] (4), [Cu(acac )(bipy)][Ni(mnt)2] (5) (Me2bipy=4,4'-二甲基-2,2'-联吡啶；mnt=马来腈二硫醇盐)。配合物 1 和 2 的分子结构相似：它们由中性 [Cu(acac)(BB)}2Ni(CN)4}] 实体，通过来自桥连配体的两个反式氰基连接两个 [Cu(acac)(BB)]+ 离子， [Ni(CN)4]2- (BB=1,10-菲咯啉和, 分别为 2,2'-联吡啶). 附着在铜离子上的有机配体之间建立的分子间
• Reactions of heteroleptic [Cu(acac)(AA)(H2O)]+ complexes with carboxylate anions (acac- = acetylacetonate, AA = 2,2’-bipyridine, 1,10-phenanthroline)
  作者：Paul A. TARABUTA、Catalin MAXIM、Marius ANDRUH

  DOI：10.33224/rrch.2021.66.1.04

  日期：——

  The reactions of [Cu(acac)(AA)(H2O)]+ species (AA = 2,2’-bipyridine, 1,10-phenanthroline) with anions derived from 4-methylphenol-2,6-dicarboxylic (H3MeIPA) and isophthalic acids (H2IPA) generate new complexes, which result by substituting the acetylacetonato ligand by carboxylato ones: [Cu(bipy)(HMeIPA)(H2O)]∙0.5H2O∙DMF 1 (DMF = dimethylformamide), 1∞[Cu(bipy)(IPA)(H2O)2]∙H2O∙DMF 2, and 1∞[Cu(phen)(IPA)(H2O)]∙DMF 3. The crystal structures of 1 - 3 have been solved. Compound 1 is a mononuclear complex, while compounds 2 and 3 are one-dimensional coordination polymers with a zigzag topology.

  [Cu(acac)(AA)(H2O)]+物种（AA = 2,2'-联吡啶，1,10-邻菲罗啉）与4-甲基苯酚-2,6-二羧酸（H3MeIPA）和异苯二甲酸（H2IPA）衍生的阴离子反应，生成通过用羧基配体替换乙酰丙酮配体而得到的新配合物：[Cu(bipy)(HMeIPA)( )]∙0.5 ∙DMF 1（DMF = 二甲基甲酰胺）、1∞[Cu(bipy)(IPA)( )2]∙ ∙DMF 2和1∞[Cu(phen)(IPA)( )]∙DMF 3。1-3的晶体结构已经被解决。化合物1是一个单核配合物，而化合物2和3是具有锯齿形拓扑结构的一维配位聚合物。
• Chemistry at the apical position of square-pyramidal copper(II) complexes: synthesis, crystal structures, and magnetic properties of mononuclear Cu(II), and heteronuclear Cu(II)–Hg(II) and Cu(II)–Co(II) complexes containing [Cu(AA)(BB)]+ moieties (AA=acetylacetonate, salicylaldehydate; BB=1,10-phenanthroline, Me2bipy=4,4′-dimethyl-2,2′-bipyridine)
  作者：Augustin M. Madalan、Victor Ch. Kravtsov、Damir Pajic、Kreso Zadro、Yurii A. Simonov、Nicolae Stanica、Lahcène Ouahab、Janusz Lipkowski、Marius Andruh

  DOI：10.1016/j.ica.2004.06.010

  日期：2004.11

  New families of mononuclear and heteropolynuclear complexes have been obtained by using [Cu(AA)(BB)](+) building-blocks (AA = acetylacetonate or salicylaldehydate; BB = 1, 10-phenanthroline, 4,4-dimethyl-2,2'-bipyridine). The following mononuclear complexes have been structurally characterized: [Cu(acac)(Me(2)bipy)]ClO4 (1), [Cu(acac)(Me(2)bipy)(NCS)] (2), [Cu(acac) (phen)(NCS)l (3). In compound 1 the copper(II) exhibits a square planar geometry, while the stereochemistry of compounds 2 and 3 is square pyramidal, with the isothiocyanato ligand coordinated in the apical position. The reaction between 2 and HgCl2 affords a trinuclear complex, [Cu(acac)(Me(2)bipy)(mu-NCS)}(2)Hg(SCN)(2)] (4). The reaction between 3 and HgCl2 leads to tetranuclear Cu2Hg2 compound, [Cu(acac)(phen)(NCS)}(2)(ClHg)(2)(NCS)(2)}] (5), with a unique structure, and to a trinuclear complex, [Cu(acac)(phen)(NCS)}(2)Hg(SCN)(2)] (6). The structure of 5 consists of a Hg-2(NCS)(2)} ring on which two [Cu(acac)(phen)(NCS)] moieties are attached. In compounds 4, 5 and 6 the mercury atoms are tetracoordinated. By reacting [Cu(sal)(Phen)(OClO3)] with (NEt4)(2)[Co(NCS)(4)], a heterohexanuclear compound is obtained: [Cu(sal)(phen)(SCN)}(2)Co(NCS)(2)](2) (7), with the following topology of the metallic centers: Cu-Co-Cu-Cu-Co-Cu. The cobalt(II) ions in 7 are tetracoordinated by nitrogen atoms arising from two bridging and two terminal thiocyanato ligands. The central copper(II) ions are bridged by the phenoxo oxygen atom arising from the sal(-) ligand. The cryomagnetic properties of compounds 2-5 and 7 have been investigated and discussed. The magnetic behavior of compounds 2-5 has been ascribed to intermolecular exchange interactions mediated by the stacking interactions. The magnetic interaction between Cu(II) and Co(II) in 7 was found ferromagnetic (J = +0.6 cm(-1)), as theoretically predicted. The exchange interactions between the central copper(II) ions is antiferromagnetic (J = -5.8 cm(-1)). (C) 2004 Elsevier B.V. All rights reserved.
• Chemistry at the apical position of square-pyramidal copper(II) complexes: Synthesis, crystal structures, and magnetic properties of homopolynuclear complexes with azido bridges containing [Cu(AA)(BB)]+ moieties (AA=acetylacetonate; BB=1,10-phenanthroline, bipy=2,2′-bipyridine)
  作者：Augustin M. Madalan、Mathias Noltemeyer、Mirela Neculai、Herbert W. Roesky、Marc Schmidtmann、Achim Müller、Yves Journaux、Marius Andruh

  DOI：10.1016/j.ica.2005.07.037

  日期：2006.1

  Three new homopolynuclear complexes with azido bridges have been obtained by using [Cu(AA)(BB)](+) building-blocks (AA = acetylacetonate; BB = 1,10-phenanthroline or 2,2'-bipyridine). The reaction between [Cu(acac)(phen)(H2O)](ClO4) and NaN3 leads to a mixture of two compounds: it binuclear complex, [(Cu(acac)(phen)}2(mu(1,3)-N-3)](ClO4)center dot 2H(2)O (1), and a linear tetranuclear one, [Cu(acae)(phen)(ClO4)}(2)Cu(phen)(mu(1,1)-N-3)(2)}(2)](2). The reaction between [Cu(acac)(bipy)(H2O)](ClO4) and NaN3 affords also a mixture of two compounds: [Cu(acac)(bipy)}(2)(mu(1,3)-N-3)](3)(ClO4)(3)center dot 3.75H(2)O (3) and [Cu(acac)(bipy)(N-3)][Cu(acac)(bipy)(H2O)](ClO4) (4). The X-ray crystal structures of compounds 1-4 have been solved (for compound 4 the crystal structure was previously reported). In compounds 1 and 3, two Cu(AA)(BB)} fragments are bridged by the azido anion in an end-to-end fashion. Two isomers, cis and trans with respect to azido bridge, were found in crystal 3. The structure of compound 2 consists of two Cu(II) central cations bridged by two mu(1,1)-azido ligands, each of them being also connected to a Cu(acac)(phen)} fragment through another mu 1,1-azido ligand. The cryomagnetic properties of the compounds 1 and 2 have been investigated and discussed. The magnetic behaviour of compound 1 shows the absence of any interactions between the metallic ions. In the tetranuclear complex 2, the magnetic interactions between the external and central copper(II) ions (J(1)), and between the central metallic ions (J(2)) were found ferromagnetic (J(1) = 0.36 cm(-1), J(2) = 7.20 cm(-1)). (c) 2005 Elsevier B.V. All rights reserved.