tris-(9-oxophenalenone)-germanium(IV) tetrakis[3,5-bis(trifluoromethyl) phenyl] borate | 872130-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tris-(9-oxophenalenone)-germanium(IV) tetrakis[3,5-bis(trifluoromethyl) phenyl] borate
• CAS: 872130-50-2
• 化学式: C₃₂H₁₂BF₂₄*C₃₉H₂₁GeO₆
• 分子量: 1521.4
• InChiKey: ZMVDVRSAJRDMJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris-(9-oxophenalenone)-germanium(IV) chloride 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 为溶剂， 以93%的产率得到tris-(9-oxophenalenone)-germanium(IV) tetrakis[3,5-bis(trifluoromethyl) phenyl] borate
  参考文献：
  名称：

  Synthesis and characterization of germanium (IV) and silicon (IV) complexes derived from 9-hydroxyphenalenone: X-ray crystal and molecular structure of tris-(9-oxophenalenone)-germanium (IV) and silicon (IV) salts

  摘要：

  The germanium (IV) and silicon (IV) complexes, tris-(9-oxophenalenone)-germanium (IV) tetrakis[3,5-bis(trifluoromethyl) phenyl] borate (7(+)TFPB(-)) and tris-(9-oxophenalenotie)-silicon (IV) tetrakis[3,5-bis(trifluoromethyl) phenyl] borate (8(+)TFPB(-)), derived from 9-hydroxyphenalenone have been synthesized and characterized by elemental analyses, infrared spectra and as well as by single crystal X-ray Study. The crystal structure of 7+TFPB- and 8+TFPB- shows a one-dimensional chain like structure and pi-overlap between the neighbouring phenalenyl planes. The cyclic voltammograms of 7(+)TFPB(-) and 8(+)TFPB(-) show three reversible oneelectron reduction steps due to the formation of the radical, anion and dianion as each phenalenyl moiety accepts an electron. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.03.097