| 164262-72-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 164262-72-0
• 化学式: C₂₂H₂₀O₆S₂Sn
• 分子量: 563.239
• InChiKey: KGZSTRXKKSDVAY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.81
• 重原子数：
  31.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  86.74
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  二甲基二氯化锡 、 silver(I) naphthalene-2-sulfonate 生成
  参考文献：
  名称：

  The synthesis and ir and NMR (1HH, 3CC AND 9Sn)Sn) spectral studies of some methyltin(IV) sulphonates

  摘要：

  Some methyltin(IV) sulphonates, Me(n)Sn(OSO(2)X)(4-n) (n = 1-3 and X = 4-tolyl and 2-naphthyl) have been prepared. The H-1, C-13 and Sn-119 NMR spectra of these compounds and the previously reported compounds, Me(3)Sn(OSO(2)X) (X = CF3, CH3 and 4-CH3C6H4) and Me(2)Sn(OSO2CH3)(2), in coordinating and non-coordinating solvents have been studied. From the chemical shifts delta(Sn-119) and the coupling constants (1)J(C-13, Sn-119) and (2)J(H-1, Sn-119), coordination number of the tin atom and the geometry of its coordination sphere have been suggested. These observations have been complemented by IR spectroscopy. Synthesis of the ternary compounds, MeSnCl(OSO(2)X)(2) (X = CH3 and 4-CH3C6H4), by reaction between Me(3)Sn(OSO(2)X) and Me(2)SnCl(2) and subsequent cleavage of the tin-carbon bond is also discussed.

  DOI：

  10.1016/0277-5387(94)00275-j