| 151637-13-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 151637-13-7
• 化学式: C₃₄H₂₂CoN₂O₂
• 分子量: 549.554
• InChiKey: XHOUWTSWLWNDBL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (R)-N,N’-bis(salicylidene)-1,1’-binaphthyl-2,2’-diamine 、 cobalt(II) diacetate tetrahydrate 以91%的产率得到
  参考文献：
  名称：

  Structural effect of cobalt Schiff base complex catalyst on its catalytic activity in dioxygenolysis of 3-methylindole

  摘要：

  Dioxygenolysis of 3-methylindole catalyzed by a series of cobalt(II) Schiff base complexes electronically and sterically designed gives 2-(N-formylamino) acetophenone as the sole product, but the reaction rate depended largely on the structure of the complex:the more positive SIGMA-degrees (Co(II)/Co(III)) brings about the more catalytic activity. Steric hindrance of coordination of the substrate to the catalyst retards the reaction.

  DOI：

  10.1016/0304-5102(93)87012-w