N-(naphthalen-2-ylmethylene)benzohydrazonothioic acid | 100146-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(naphthalen-2-ylmethylene)benzohydrazonothioic acid
• CAS: 100146-14-3
• 化学式: C₁₈H₁₄N₂S
• 分子量: 290.389
• InChiKey: MRYCJCJDUJQMCF-UHFFFAOYSA-N

物化性质

• 沸点：
  464.4±28.0 °C(Predicted)
• 密度：
  1.13±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.14
• 重原子数：
  21.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.39
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  N-(naphthalen-2-ylmethylene)benzohydrazonothioic acid 、 cadmium(II) chloride 在 NH₃ 作用下， 以 甲醇 、 水 为溶剂， 以>99的产率得到{Cd(SC(C6H5)NNCH-2-C10H7)2}
  参考文献：
  名称：

  Zelenin, K. N.; Khorseeva, L. A.; Alekseev, V. V., Journal of general chemistry of the USSR, 1990, vol. 60, p. 2099 - 2112

  摘要：

  DOI：

文献信息

• Jensen,K.A.; Pedersen,C., Acta Chemica Scandinavica (1947), 1961, vol. 15, p. 1097 - 1103
  作者：Jensen,K.A.、Pedersen,C.

  DOI：——

  日期：——
• Synthesis and characterization of gallium complexes bearing N-arylmethylenethiobenzahydrazone ligands; crystal structure of diethyl[N-(4-N,N-dimethylamino)benzylidene thiobenzahydrazonato]gallium
  作者：Yingzhong Shen、Yiying Zhang、Ye Li、Xian Tao、Yan Wang

  DOI：10.1016/j.ica.2006.08.041

  日期：2007.4

  Five diethylgallium complexes of type Et2GaL [(L = N-(4-methoxy) benzylidenethiobenzahydrazonato (1), N-(3,4-dimethoxy)benzylidenethio benzahydrazonato (2), N-(4-N,N-dimethylamino)benzylidenethiobenza hydrazonato (3), N-(2-naphthyl)methylenethiobenzahydrazonato (4), N-(9-anthryl)methylenethiobenzahydrazonato (5)] have been synthesized by the reaction of triethylgallium with appropriate N-arylmethylene thiobenzahydrazones. The compounds obtained have been characterized by elemental analysis, H-1 NMR, IR and mass spectroscopies, respectively. The solid structure of 3 has been determined by X-ray single crystal analysis, in which Ga atom is four coordinate. The photoluminescent property of complex I was studied. The maximum emission wavelength is 475 nm upon radiation by UV light. (c) 2006 Elsevier B.V. All rights reserved.