(NO3)2Cu(7,9:16,18-dinaphthyl-1,3,4,6,10,12,13,15-octaazacyclooctadecane-1,5,10,14-tetraene) | 1263407-16-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (NO3)2Cu(7,9:16,18-dinaphthyl-1,3,4,6,10,12,13,15-octaazacyclooctadecane-1,5,10,14-tetraene)
• CAS: 1263407-16-4
• 化学式: C₂₈H₂₈CuN₁₀O₆
• 分子量: 664.14
• InChiKey: SMWAQPLROKRUBM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  7,9:16,18-dinaphthyl-1,3,4,6,10,12,13,15-octaazacyclooctadecane-1,5,10,14-tetraene 、 copper(II) nitrate 以 甲醇 为溶剂， 以65%的产率得到(NO3)2Cu(7,9:16,18-dinaphthyl-1,3,4,6,10,12,13,15-octaazacyclooctadecane-1,5,10,14-tetraene)
  参考文献：
  名称：

  Synthesis, Physicochemical, and Antimicrobial Screening Studies of Complexes of Co(II), Ni(II), Cu(II), and Zn(II) with 18-membered Schiff Base Octaazamacrocyclic Ligand

  摘要：

  A [2 + 2] condensation reaction between 1,8-diaminonaph-thalene and N,N'-diacetylhydrazine in 1:1 molar ratio in methanol resulted in a novel Schiff base macrocyclic ligand, (L): 7,9:16,18-dinaphthyl-1,3,4,6,10,12,13,15-octaazacyclooctadecane-1,5,10,14-tetraene. Metal complexes have been synthesized by the reaction of L with the corresponding metal salts. The results of elemental analyses, ESI-mass, and Job's method ascertain their stoichiometry while the spectral data obtained from 1H and 13C NMR, and IR confirmed their bonding features. However, the stereochemistry was inferred from the UV-visible, EPR, and magnetic moment studies. The ligand and its complexes were screened in vitro against gram positive bacteria, gram negative bacteria, and fungi.

  DOI：

  10.1080/15533174.2010.522650