| 1313037-11-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1313037-11-4
• 化学式: C₆₀H₅₁N₃Ni₃O₆S₃
• 分子量: 1182.35
• InChiKey: PYNIMANPEVVSCF-KGUBRXDJSA-H

反应信息

• 作为反应物：
  描述：

  、 足球烯 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Metallohosts with a Heart of Carbon

  摘要：

  Single-crystal X-ray diffraction studies have confirmed that Ni3S3-based molecular bowls prepared in one-pot reactions capture either CH2Cl2 or C-60. The nature of the pendant substituents (naphthalen-2-ylmethyl, benzyl, or ethyl) around the rim of the bowl dictates the formation of a 1:1 (bowl host-C-60 guest) or 2:1 (capsule host-C-60 guest) architecture. In CDCl3, the trimeric complexes were found to be in equilibrium with dimeric analogues. For the naphthalen-2-ylmethyl-substituted host, NMR spectroscopic titration data confirmed a 1:1 host-C-60 guest complex in 1,2-Cl2C6D4 solution.

  DOI：

  10.1021/ja204888w