[(acetonyl)PdCl(dimethyl sulfoxide)2] | 351376-58-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: [(acetonyl)PdCl(dimethyl sulfoxide)2]
• 英文别名: chloropalladium(1+);methylsulfinylmethane;propan-2-one
• CAS: 351376-58-4
• 化学式: C₇H₁₇ClO₃PdS₂
• 分子量: 355.215
• InChiKey: ZMJPFAZJVYFKFS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(acetonyl)PdCl(dimethyl sulfoxide)2] 以 乙醚 、 丙酮 为溶剂， 生成 [Pd2(acetonyl)(μ-κ2-C,O-CH2C(O)Me)(μ-Cl)Cl(dimethyl sulfoxide)2]
  参考文献：
  名称：

  [Pd{CH₂C(O)Me}Cl]_n, a Key Product for the Synthesis of Acetonylpalladium(II) Complexes

  摘要：

  [Hg{CH2C(O)Me}(2)] reacts with [PdCl2(MeCN)(2)] (1:1) or with (Me4N)(2)[Pd2Cl6] (2:1) to give [Pd{CH2C(O)Me}Cl](n), which can be used to prepare a variety of acetonyl complexes. Thus, by reacting it; with the appropriate ligands, complexes [Pd{CH2C(O)Me}I](n), [Pd{CH2C(O)-Me}CIL2] [L-2 = N,N,N 'N ' -tetramethylethylenediamine, 2,2 ' -bipyridine, 4,4 '-(Bu-t)(2)-2,2 ' -bipyridine, 1,10-phenathroline; L = PPh3, dimethyl sulfoxide (dmso)], [Pd-2{CH2C(O)Me}{mu-kappa (2)-C,O-CH2C(O)Me}(mu -Cl)Cl(dmso)(2)], or [Pd-2{CH2C(O)Me}(2)(mu -Cl)(2)(tetrahydrothiophene)(2)] can be obtained. The crystal structures of the last two complexes and that of [Hg{CH2C(O)Me}(2)] have been determined by X-ray crystallography.

  DOI：

  10.1021/om0101036
• 作为产物：
  描述：

  二甲基亚砜 、 [Pd(acetonyl)Cl] 以 丙酮 为溶剂， 以80%的产率得到[(acetonyl)PdCl(dimethyl sulfoxide)2]
  参考文献：
  名称：

  [Pd{CH₂C(O)Me}Cl]_n, a Key Product for the Synthesis of Acetonylpalladium(II) Complexes

  摘要：

  [Hg{CH2C(O)Me}(2)] reacts with [PdCl2(MeCN)(2)] (1:1) or with (Me4N)(2)[Pd2Cl6] (2:1) to give [Pd{CH2C(O)Me}Cl](n), which can be used to prepare a variety of acetonyl complexes. Thus, by reacting it; with the appropriate ligands, complexes [Pd{CH2C(O)Me}I](n), [Pd{CH2C(O)-Me}CIL2] [L-2 = N,N,N 'N ' -tetramethylethylenediamine, 2,2 ' -bipyridine, 4,4 '-(Bu-t)(2)-2,2 ' -bipyridine, 1,10-phenathroline; L = PPh3, dimethyl sulfoxide (dmso)], [Pd-2{CH2C(O)Me}{mu-kappa (2)-C,O-CH2C(O)Me}(mu -Cl)Cl(dmso)(2)], or [Pd-2{CH2C(O)Me}(2)(mu -Cl)(2)(tetrahydrothiophene)(2)] can be obtained. The crystal structures of the last two complexes and that of [Hg{CH2C(O)Me}(2)] have been determined by X-ray crystallography.

  DOI：

  10.1021/om0101036