[Eu(m-bromobenzoate)3(1,10-phenanthroline)(H2O)]2 | 538327-15-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Eu(m-bromobenzoate)3(1,10-phenanthroline)(H2O)]2
• 英文别名: [Eu(m-BrBA)3(H2O)(phen)]2
• CAS: 538327-15-0
• 化学式: C₆₆H₄₄Br₆Eu₂N₄O₁₄
• 分子量: 1900.44
• InChiKey: KRNNYCHBEKVXPS-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Eu(m-bromobenzoate)3(1,10-phenanthroline)(H2O)]2 以 neat (no solvent) 为溶剂， 生成 europium(III) oxide
  参考文献：
  名称：

  Crystal structure and properties of complex [Eu(m-BrBA)3(H2O)(phen)]2

  摘要：

  A binuclear europium complex [Eu(m-BrBA)(3)(H2O)(phen)](2) (1) has been obtained in the ethanol solution and characterized structurally by X-ray diffraction, where m-BrBA = m-bromobenzoate and phen = 1, 10-phenanthroline. Each Eu3+ ion is eight-coordinated to one 1,10-phenaDthroline molecule, one monodentate carboxylate group, one water molecule and four bridging carboxylate groups in which the carboxylate groups are bonded to the europium ion in two modes: the monodentate and the bridging bidentate. Excitation and luminescence data observed at room temperature show that the title complex emits red fluorescence under ultraviolet light. The results of thermal analysis indicate that the complex [Eu(m-BrBA)(3)(H2O)(phen)](2) is quite stable to heat. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00017-6
• 作为产物：
  描述：

  1,10-菲罗啉 、 europium(III) chloride hexahydrate 、 间溴苯甲酸 在 NaOH 作用下， 以 乙醇 为溶剂， 生成 [Eu(m-bromobenzoate)3(1,10-phenanthroline)(H2O)]2
  参考文献：
  名称：

  Crystal structure and properties of complex [Eu(m-BrBA)3(H2O)(phen)]2

  摘要：

  A binuclear europium complex [Eu(m-BrBA)(3)(H2O)(phen)](2) (1) has been obtained in the ethanol solution and characterized structurally by X-ray diffraction, where m-BrBA = m-bromobenzoate and phen = 1, 10-phenanthroline. Each Eu3+ ion is eight-coordinated to one 1,10-phenaDthroline molecule, one monodentate carboxylate group, one water molecule and four bridging carboxylate groups in which the carboxylate groups are bonded to the europium ion in two modes: the monodentate and the bridging bidentate. Excitation and luminescence data observed at room temperature show that the title complex emits red fluorescence under ultraviolet light. The results of thermal analysis indicate that the complex [Eu(m-BrBA)(3)(H2O)(phen)](2) is quite stable to heat. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00017-6