Dithiophosphoric acid O,O'-dinaphthalen-1-yl ester | 50566-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Dithiophosphoric acid O,O'-dinaphthalen-1-yl ester
• CAS: 50566-50-2
• 化学式: C₂₀H₁₅O₂PS₂
• 分子量: 382.444
• InChiKey: GCDJYVDLUBSDOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.61
• 重原子数：
  25.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.46
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  Dithiophosphoric acid O,O'-dinaphthalen-1-yl ester 在 sodium 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以88.55%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of O,O'-Bis(α-Naphthyl, β-Naphthyl, and 2, 3, 5-Trimethylphenyl)Dithiophosphate Ligands

  摘要：

  O,O'-Bis(alpha-Naphthyl, beta-Naphthyl and 2,3,5-trimethylphenyl) dithiophosphate ligands have been isolated as triethylammonium salts, (alpha-C10H7O-, beta-C10H7O, and (CH3)(3)C6H2O)(2)PS2HNEt3, by the reaction of alpha-C10H7OH, beta-C10H7OH, or (CH3)(3)C6H2OH with P2S5 in presence of Et3N, in 4:1:2 molar ratio in chloroform under anhydrous conditions. Acidic form of these ligands, (alpha-C10H7O-, beta-C10H7O-, or (CH3)(3)C6H2O)(2)PS2H, have been obtained by the direct reaction of alpha-C10H7OH, beta-C10H7OH-, or (CH3)(3)C6H2OH with P2S5 in 4:1 molar ratio in presence of microwaves under solvent-free conditions. Both forms of the ligands have been converted into corresponding sodium salts, (alpha-C10H7O-, beta-C10H7O-, or (CH3)(3)C6H2O)(2)PS2Na. These compounds have been characterized by elemental analyses (C, H, N, and S) and mass, IR, and NMR (H-1, C-13 and P-31) spectroscopic studies.Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

  DOI：

  10.1080/10426507.2012.680081
• 作为产物：
  描述：

  萘酚 在 tetraphosphorus decasulfide 作用下， 反应 0.07h， 以99.3%的产率得到Dithiophosphoric acid O,O'-dinaphthalen-1-yl ester
  参考文献：
  名称：

  Synthesis and Characterization of O,O'-Bis(α-Naphthyl, β-Naphthyl, and 2, 3, 5-Trimethylphenyl)Dithiophosphate Ligands

  摘要：

  O,O'-Bis(alpha-Naphthyl, beta-Naphthyl and 2,3,5-trimethylphenyl) dithiophosphate ligands have been isolated as triethylammonium salts, (alpha-C10H7O-, beta-C10H7O, and (CH3)(3)C6H2O)(2)PS2HNEt3, by the reaction of alpha-C10H7OH, beta-C10H7OH, or (CH3)(3)C6H2OH with P2S5 in presence of Et3N, in 4:1:2 molar ratio in chloroform under anhydrous conditions. Acidic form of these ligands, (alpha-C10H7O-, beta-C10H7O-, or (CH3)(3)C6H2O)(2)PS2H, have been obtained by the direct reaction of alpha-C10H7OH, beta-C10H7OH-, or (CH3)(3)C6H2OH with P2S5 in 4:1 molar ratio in presence of microwaves under solvent-free conditions. Both forms of the ligands have been converted into corresponding sodium salts, (alpha-C10H7O-, beta-C10H7O-, or (CH3)(3)C6H2O)(2)PS2Na. These compounds have been characterized by elemental analyses (C, H, N, and S) and mass, IR, and NMR (H-1, C-13 and P-31) spectroscopic studies.Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

  DOI：

  10.1080/10426507.2012.680081

文献信息

• Transition metal complexes of organothiophosphorous ligands V.Some aryl esters and amides of dithiophosphoric acid and their nickel(II) and cobalt(II and III)complexes
  作者：R. Micu-Semeniuc、L. Dumitrescu-Silaghi、I. Haiduc

  DOI：10.1016/s0020-1693(00)89489-x

  日期：1979.1

  decasulfide reacted with phenoxyethanol, α and β-naphthol, ortho-toluidine, ortho-aminophenol and ortho-phenylenediamine to give aryl esters or amides of dithiophosphoric acids. These were used as ligands in the synthesis of some nickel(II) and cobalt(II and III) complexes. With para-toluidine only the amide (p-CH3C6H4NH)3PS was isolated.

  摘要四磷十硫化碳与苯氧基乙醇，α和β-萘酚，邻甲苯胺，邻氨基苯酚和邻苯二胺反应，生成二硫代磷酸的芳基酯或酰胺。这些在某些镍（II）和钴（II和III）配合物的合成中用作配体。用对甲苯胺仅分离出酰胺（p-CH 3 C 6 H 4 NH）3 PS。