(C6F5)ClB(CPh2(C6F5)) | 1351866-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: (C6F5)ClB(CPh2(C6F5))
• 英文别名: Chloro-(2,3,4,5,6-pentafluorophenyl)-[(2,3,4,5,6-pentafluorophenyl)-diphenylmethyl]borane；chloro-(2,3,4,5,6-pentafluorophenyl)-[(2,3,4,5,6-pentafluorophenyl)-diphenylmethyl]borane
• CAS: 1351866-35-7
• 化学式: C₂₅H₁₀BClF₁₀
• 分子量: 546.602
• InChiKey: YQQNJPLQEUDFSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.09
• 重原子数：
  37
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  氯[二(五氟苯基)]硼烷 、 二苯基重氮甲烷 以 not given 为溶剂， 以97%的产率得到(C6F5)ClB(CPh2(C6F5))
  参考文献：
  名称：

  Insertion Reactions of Diazomethanes and Electrophilic Boranes

  摘要：

  The electrophilic pentafluoroarylboranes B-(C6F5)(3), PhB(C6F5)(2), and ClB(C6F5)(2) react with (trimethylsilyl) diazomethane, diphenyldiazomethane, or (pentafluorophenyl)diazomethane, affording insertion into the one or two B-C bonds in a facile and high-yielding route to the boranes (Me3SiCH(C6F5))B(C6F5)(2), (Me3SiCH-(C6F5))(2)B(C6F5), (Me3SiCH(C6F5))(Me3SiCH(Ph))B-(C6F5), (C6F5)ClB(CPh2(C6F5)), and (C6F5)(2)B(CH(C6F5)(2)).

  DOI：

  10.1021/om2011613

文献信息

• Insertion Reactions of Diazomethanes and Electrophilic Boranes
  作者：Rebecca C. Neu、Douglas W. Stephan

  DOI：10.1021/om2011613

  日期：2012.1.9

  The electrophilic pentafluoroarylboranes B-(C6F5)(3), PhB(C6F5)(2), and ClB(C6F5)(2) react with (trimethylsilyl) diazomethane, diphenyldiazomethane, or (pentafluorophenyl)diazomethane, affording insertion into the one or two B-C bonds in a facile and high-yielding route to the boranes (Me3SiCH(C6F5))B(C6F5)(2), (Me3SiCH-(C6F5))(2)B(C6F5), (Me3SiCH(C6F5))(Me3SiCH(Ph))B-(C6F5), (C6F5)ClB(CPh2(C6F5)), and (C6F5)(2)B(CH(C6F5)(2)).