(+)-(S)-(E)-[1-(2-methoxynaphthalen-1-ylsulfinyl)hex-1-enyl]tributylstannane | 1211944-69-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (+)-(S)-(E)-[1-(2-methoxynaphthalen-1-ylsulfinyl)hex-1-enyl]tributylstannane
• CAS: 1211944-69-2
• 化学式: C₂₉H₄₆O₂SSn
• 分子量: 577.459
• InChiKey: MRZYGEZIHPSVKV-YFDXKITBSA-N

反应信息

• 作为反应物：
  描述：

  (+)-(S)-(E)-[1-(2-methoxynaphthalen-1-ylsulfinyl)hex-1-enyl]tributylstannane 在 碘 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以89%的产率得到(-)-(S)-(E)-(2-methoxynaphthalen-1-ylsulfinyl)-1-iodohex-1-ene
  参考文献：
  名称：

  Sulfoxide-Directed Intramolecular [4 + 2] Cycloadditions between 2-Sulfinyl Butadienes and Unactivated Alkynes

  摘要：

  Sulfinyl dienynes undergo thermal and catalyzed IMDA cycloadditions, often at room temperature, to produce cyclohexa-1,4-dienes with good yields and high selectivities. Additionally, the products preserve a synthetically useful vinyl sulfoxide functionality. The selective manipulation of the double bonds in the cycloadducts has also been examined in this work.

  DOI：

  10.1021/jo9024489