n-dodecyloxy-2-naphthalene | 78904-64-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: n-dodecyloxy-2-naphthalene
• 英文别名: dodecyl-[2]naphthyl ether；Dodecyl-[2]naphthyl-aether；2-Dodecyloxy-naphthalin；2-(Dodecyloxy)naphthalene；2-dodecoxynaphthalene
• CAS: 78904-64-0
• 化学式: C₂₂H₃₂O
• 分子量: 312.495
• InChiKey: SGZSHWXSWILTIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  23
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  n-dodecyloxy-2-naphthalene 在 乙醇 、 镍 作用下， 130.0 ℃ 、19.61 MPa 条件下， 生成 dodecyl-(1,2,3,4-tetrahydro-[2]naphthyl)-ether
  参考文献：
  名称：

  The Selective Hydrogenation of Derivatives of Naphthalene and Diphenyl

  摘要：

  DOI：

  10.1021/ja01270a049
• 作为产物：
  描述：

  sodium 2-naphtholate 、 溴代十二烷 生成 n-dodecyloxy-2-naphthalene
  参考文献：
  名称：

  The Selective Hydrogenation of Derivatives of Naphthalene and Diphenyl

  摘要：

  DOI：

  10.1021/ja01270a049

文献信息

• A two-stage conversion of primary-alkyl primary-amines into alcohols and further examples of transfunctionalisation of amines under mild conditions
  作者：Alan R. Katritzky、Antonio Saba、Ranjan C. Patel

  DOI：10.1039/p19810001492

  日期：——

  Phase-transfer catalysts allow the conversion of primary-alkyl primary-amines into primary alcohols, sulphones, sulphides, and ethers at ⩽ 100 °C via the pentacyclic pyridiniums (9).

  相转移催化剂可在约100°C下通过五环吡啶鎓将伯烷基伯胺转化为伯醇，砜，硫化物和醚（9）。
• Novel substituted naphthalene compounds and liquid crystal compositions containing same
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0332409A2

  公开（公告）日：1989-09-13

  In accordance with the present invention, there are provided substituted naphthalene compounds of formula [I]. wherein R¹ represents alkyl of 1-18 carbon atoms, R² represents alkyl of 1-18 carbon atoms, X is -OCH₂- or -CH₂CH₂-, and n is 0 or 1. The invention also provides liquid crystal compositions containing a substituted naphthalene compound such as a compound of formula [I].

  根据本发明，提供了式[I]的取代萘化合物。 其中 R¹ 代表 1-18 个碳原子的烷基，R² 代表 1-18 个碳原子的烷基，X 为 -OCH₂- 或 -CH₂CH₂-，n 为 0 或 1。 本发明还提供了含有取代萘化合物（如式 [I] 的化合物）的液晶组合物。
• Acting energy radiation curable ink-jet ink, ink-jet recoring method, and printed matter
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2228415A1

  公开（公告）日：2010-09-15

  The present invention provides an actinic energy radiation curable ink-jet ink exhibiting excellent ink storage stability, nozzle ink repellency, and ejection stability, and also exhibiting excellent curability, anti-abrasion properties, solvent resistance, flexibility, weather resistance, and substrate adhesion properties even under various ambience factors and irradiation conditions, as well as an ink-jet recording method and printed matter using the same. In an actinic energy radiation curable ink-jet ink containing a cationically polymerizable compound and a photo-cationic polymerization initiator, an actinic energy radiation curable ink-jet ink wherein a cationically polymerizable compound having a vinyl ether group as a reactive group is contained at 50.0% by mass or more and the halogen ion content is 1.0 µg/g of the ink - 100 µg/g of the ink.

  本发明提供了一种在各种环境因素和辐照条件下都能表现出优异的储墨稳定性、喷嘴拒墨性和喷出稳定性，并且还能表现出优异的固化性、抗磨损性、耐溶剂性、柔韧性、耐候性和基材附着性的可辐射固化喷墨墨水，以及使用该墨水的喷墨记录方法和印刷品。在含有阳离子可聚合化合物和光阳离子聚合引发剂的可辐射固化喷墨墨水中，阳离子可聚合化合物中具有乙烯基醚基团作为活性基团的阳离子可聚合化合物的质量含量为 50.0% 或以上，卤素离子含量为 1.0 µg/g - 100 µg/g。
• Actinic energy radiation curable ink-jet ink and ink-jet image forming method
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2236568A1

  公开（公告）日：2010-10-06

  Provided is an actinic energy radiation curable ink-jet ink, an ink-jet recording method, and printed matter satisfying ink storage stability, ejection stability, weather resistance, flexibility, safety, odorless properties. An actinic energy radiation curable ink-jet ink comprises a cationically polymerizable compound and a photo-cationic polymerization initiator, wherein the cationically polymerizable compound comprises a vinyl ether group as a. reactive group, the photo-cationic polymerization initiator is a photo acid generator, a amount of generation of protonic acid from the photo acid generator is 1 x 10-4 mol/L or less, and comprising a radical polymerization inhibitor; wherein the amount of generation of protonic acid is defined as a difference of a hydrogen ion concentration (mol/L) in dioxane solution between immediately after preparation and after refluxing when 0.02 mol/L of the photo acid generator in dioxane solution are refluxed 20 hours under atmospheric pressure.

  本发明提供了一种可辐射固化的喷墨墨水、一种喷墨记录方法以及满足墨水储存稳定性、弹射稳定性、耐候性、柔韧性、安全性和无味特性的印刷品。一种可辐射固化的喷墨墨水由阳离子可聚合化合物和光阳离子聚合引发剂组成，其中阳离子可聚合化合物由乙烯基醚基作为反应基团，光阳离子聚合引发剂由乙烯基醚基作为反应基团。其中，阳离子可聚合化合物由乙烯基醚基团作为反应基团，光阳离子聚合引发剂是一种光酸发生剂，光酸发生剂生成质子酸的量为 1 x 10-4 mol/L 或更少，还包括一种自由基聚合抑制剂；其中，质子酸的生成量定义为在大气压下将 0.02 mol/L 的光酸发生剂在二噁烷溶液中回流 20 小时后，制备后立即与回流后二噁烷溶液中氢离子浓度（mol/L）之差。
• Image forming method using actinic energy radiation curable ink-jet ink and printed matter obtained thereby
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2266812A2

  公开（公告）日：2010-12-29

  Provided is an actinic radiation curable inkjet ink capable of high sensitivity and high glossy image; and an image forming method utilizing the same. An actinic radiation curable inkjet ink comprising a photo polymerization initiator and a polymerizable monomer, wherein a surface free energy γs of an ink layer cured by an actinic radiation is in the range of 30 to 50 mJ/m2 and a polar component γsp is in the range of 5 to 15 mJ/m2; wherein γsd, γsp and γsh each represent a non-polar component, a polar component and a hydrogen bond component of a surface free energy of a solid surface based on Young-Fowkes Equation, provided that the surface free energy is represented by γs=γsd+γsp+γsh.

  本发明提供了一种能产生高灵敏度和高光泽度图像的光辐射固化喷墨墨水，以及利用该墨水的图像形成方法。一种光辐射固化喷墨墨水，由光聚合引发剂和可聚合单体组成，其中光辐射固化墨层的表面自由能 γs 在 30 至 50 mJ/m2 之间，极性分量 γsp 在 5 至 15 mJ/m2 之间；其中，γsd、γsp 和 γsh 分别代表基于 Young-Fowkes 方程的固体表面自由能的非极性分量、极性分量和氢键分量，条件是表面自由能由γs=γsd+γsp+γsh 表示。