(-)-(R)-1-hexynyl 2-methoxynaphthalen-1-yl sulfoxide | 1211944-55-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (-)-(R)-1-hexynyl 2-methoxynaphthalen-1-yl sulfoxide
• CAS: 1211944-55-6
• 化学式: C₁₇H₁₈O₂S
• 分子量: 286.395
• InChiKey: PTDYGTLQCBPMKD-HXUWFJFHSA-N

反应信息

• 作为产物：
  描述：

  (-)-menthyl 2-methoxynaphthalenesulfinate 、 1-己炔 在 溴乙烷 、 magnesium 作用下， 以 乙醚 、 甲苯 为溶剂， 反应 2.0h， 以75%的产率得到(-)-(R)-1-hexynyl 2-methoxynaphthalen-1-yl sulfoxide
  参考文献：
  名称：

  Sulfoxide-Directed Intramolecular [4 + 2] Cycloadditions between 2-Sulfinyl Butadienes and Unactivated Alkynes

  摘要：

  Sulfinyl dienynes undergo thermal and catalyzed IMDA cycloadditions, often at room temperature, to produce cyclohexa-1,4-dienes with good yields and high selectivities. Additionally, the products preserve a synthetically useful vinyl sulfoxide functionality. The selective manipulation of the double bonds in the cycloadducts has also been examined in this work.

  DOI：

  10.1021/jo9024489