[europium(III)(acetate)3(1,10-phenanthroline)]2 | 219502-93-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [europium(III)(acetate)3(1,10-phenanthroline)]2
• 英文别名: Tetra-mu-acetato-kappa^4^O:O';kappa^3^O,O': O;kappa^3^O:O,O'-bis[(acetato-kappa^2^O,O')(1,10-phenanthroline-kappa^2^N,N')europium(III)] bis(mu-acetato-kappa^3^O,O':O')bis(mu-acetato-kappa^2^O:O')；europium(3+);1,10-phenanthroline;hexaacetate
• CAS: 219502-93-9
• 化学式: C₃₆H₃₄Eu₂N₄O₁₂
• 分子量: 1018.61
• InChiKey: UHFICDRYZYVYPF-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -1.9
• 重原子数：
  54
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  292
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 europium(III) acetate hydrate 以 乙醇 、 水 为溶剂， 生成 [europium(III)(acetate)3(1,10-phenanthroline)]2
  参考文献：
  名称：

  Spectra and details of the structure of europium aliphatic carboxylates with 1,10-phenanthroline derivatives

  摘要：

  Luminescence, excitation of luminescence, IR and Raman spectra of a variety of carboxylates Eu(RCOO)(3). Phen (Phen-1,10-phenanthroline) consisting of acetate, propionate, lactate, capronate compounds, and Eu(CH3COO)(3). Ph (Ph-six 1,10-phenanthroline derivatives) were examined. Crystal field parameters for model compounds were calculated. The crystal structure of the europium acetate Eu(CH3COO)(3). Phen was solved by X-ray method. Dependence of the spectroscopic characteristics on variation of both types of ligands, indicating details of the structure of compounds, was examined. Reciprocal influence of inequivalent ligands in europium carboxylates was analysed. It was demonstrated that steric factors are as significant as the donor-acceptor properties of the ligands in creation of the structure of compounds under investigation. (C) 2002 Elsevier Science B V All rights reserved.

  DOI：

  10.1016/s0925-8388(02)00031-2