silver(I) 2-(perfluorophenyl)acetate | 151228-81-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: silver(I) 2-(perfluorophenyl)acetate
• CAS: 151228-81-8
• 化学式: Ag*C₈H₂F₅O₂
• 分子量: 332.963
• InChiKey: BIUVNZZYZDGBBU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.67
• 重原子数：
  16.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  silver(I) 2-(perfluorophenyl)acetate 以 neat (no solvent) 为溶剂， 生成 银
  参考文献：
  名称：

  Thermal and spectroscopic studies of the Ag(I) salts with fluorinated carboxylic and sulfonic acid residues

  摘要：

  Silver(I) salts with RCOOH, where R is CF3(CF2)2, CF3(CF2)6, CF3(CF2)8, C6F5, C6F5CH2, with RSO3H, where R is CF3, CF3(CF2)3, and with HOOC(CF2)3COOH were synthesized. The thermal decomposition processes were studied and the activation energies calculated from thermal data. The decomposition mechanisms and thermal stabilities are discussed. From the IR, and C-13 and F-19 NMR measurements, it is proposed that the carboxylic acid residues have monodentate bonding.

  DOI：

  10.1016/0040-6031(93)80136-x
• 作为产物：
  描述：

  5-氟苯乙酸 、 silver carbonate 以 not given 为溶剂， 生成 silver(I) 2-(perfluorophenyl)acetate
  参考文献：
  名称：

  Thermal and spectroscopic studies of the Ag(I) salts with fluorinated carboxylic and sulfonic acid residues

  摘要：

  Silver(I) salts with RCOOH, where R is CF3(CF2)2, CF3(CF2)6, CF3(CF2)8, C6F5, C6F5CH2, with RSO3H, where R is CF3, CF3(CF2)3, and with HOOC(CF2)3COOH were synthesized. The thermal decomposition processes were studied and the activation energies calculated from thermal data. The decomposition mechanisms and thermal stabilities are discussed. From the IR, and C-13 and F-19 NMR measurements, it is proposed that the carboxylic acid residues have monodentate bonding.

  DOI：

  10.1016/0040-6031(93)80136-x