[1,8-(NSiMe₃)₂C₁₀H₆]BiNPhCONMe₂ | 1399357-97-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [1,8-(NSiMe₃)₂C₁₀H₆]BiNPhCONMe₂
• 英文别名: bismuth;N,N-dimethyl-N'-phenylcarbamimidate;trimethylsilyl-(8-trimethylsilylazanidylnaphthalen-1-yl)azanide
• CAS: 1399357-97-1
• 化学式: C₂₅H₃₅BiN₄OSi₂
• 分子量: 672.731
• InChiKey: FSNCOGCMWGKFHG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.74
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  40.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  异氰酸苯酯 、 (1,8-bis[(trimethylsilyl)amino]naphthalene)(dimethylaminobismuth) 以 正己烷 为溶剂， 反应 12.0h， 以69%的产率得到[1,8-(NSiMe₃)₂C₁₀H₆]BiNPhCONMe₂
  参考文献：
  名称：

  Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity

  摘要：

  The organobismuth(III) and dibismuthine complexes bearing N,N'-disubstituted 1,8-diaminonaphthalene ligand were prepared. The reaction of LBiNMe2 (1) [L = 1,8-(NSiMe3)(2)C10H6] with ClSiMe3 results in the elimination of Me3SiNMe2, while PhCCH, Cp*H, and PhOH proceed via HNMe2 elimination and provide the complexes of LBiCl (2), LBiCCPh (3), LBiCp*(4), and LBiOPh (5), respectively. Reaction of 1 with AlMe3 in n-hexane yields LBiMe (6). Compound 1 reacts with diisopropylcarbodiimide and phenyl isocyanate under insertion at the Bi-NMe2 bond to give the addition products LBi(NiPr)(2)CNMe2 (7) and LBiN(Ph)C(O)NMe2 (8). The reactions of 1 with sulfur and PhSiH3 result in the formation of LBi-S-BiL (9) and LBi-BiL (10), respectively. Compounds 2-10 were characterized by elemental analysis, H-1, C-13, and Si-29 NMR spectroscopy, and X-ray crystallographic studies.

  DOI：

  10.1021/om300758s