An improved process for producing poly(arylene sulfide sulfone) of increased molecular weight is provided. The process employs an Li salt of C₁ - C₂₀ carboxylic acid as a polymerization auxiliary and is carried out in an organic amide solvent by reacting a dihalogenated aromatic sulfone with an alkali metal sulfide in the presence of 10 - 15 moles of water per mole of the alkali metal sulfide at temperatures within the range of from 160°C to 230°C.
本发明提供了一种生产分子量增大的聚芳基砜的改进工艺。该工艺采用 C₁ - C₂₀
羧酸的
锂盐作为聚合助剂,在有机酰胺溶剂中进行,方法是在每摩尔碱
金属
硫化物含有 10-15 摩尔
水的情况下,在 160°C 至 230°C 的温度范围内,使二卤化芳砜与碱
金属
硫化物反应。