5-chloro-2-(2-hydroxy-5-tert-octylphenyl)-2H-benzotriazole | 23514-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-chloro-2-(2-hydroxy-5-tert-octylphenyl)-2H-benzotriazole
• 英文别名: 5-chloro-2-(2'-hydroxy-5'-tert-octylphenyl)benzotriazole；2-(5-chloro-benzotriazol-2-yl)-4-(1,1,3,3-tetramethyl-butyl)-phenol；2-(5-Chlorobenzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol
• CAS: 23514-74-1
• 化学式: C₂₀H₂₄ClN₃O
• 分子量: 357.883
• InChiKey: OMUFLZDKJGZMRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  50.9
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Processes for the preparation of benzotriazole UV absorbers
  申请人：——

  公开号：US20020035175A1

  公开（公告）日：2002-03-21

  Provided is a process for preparing 2H-benzotriazole UV absorbers containing a perfluoroalkyl moiety at the 5-position of the benzo ring, for example a trifluoromethyl group, which involves diazotizing the perfluoroalkyl substituted o-nitroaniline using concentrated sulfuric acid plus sodium nitrite or nitrosylsulfuric acid to form the corresponding monoazobenzene intermediate via the diazonium salt intermediate which is reduced to the corresponding 5-perfluoroalkyl substituted 2H-benzotriazole UV absorber compound by conventional reduction means. Also provided is a novel one-pot, multiphase reaction for the preparation of 2(2-nitrophenylazo) substituted phenols, which are precursors for 2H-benzotriazole UV absorbers.

  提供了一种制备在苯环的5位含有全氟烷基基团（例如三氟甲基基团）的2H-苯并三唑紫外吸收剂的方法，该方法涉及使用浓硫酸加硝酸钠或亚硝基硫酸制备全氟烷基取代的邻硝基苯胺，以形成相应的单氮偶联苯中间体，通过传统还原手段将二氮盐中间体还原为相应的5-全氟烷基取代的2H-苯并三唑紫外吸收剂化合物。还提供了一种用于制备2(2-硝基苯基偶氮)取代酚的新型一锅多相反应，这些化合物是2H-苯并三唑紫外吸收剂的前体。
• Ultraviolet light absorbing ketones of 2-(2-Hydroxyphenyl) benzotriazole
  申请人：Chang Chia-Hu

  公开号：US20100086500A1

  公开（公告）日：2010-04-08

  The invention relates to ultraviolet light absorbing compounds, their preparation and uses as protective agents and stabilizers in coatings, plastics and topically applied products. The compounds are ketone derivatives of 2-(2-hydroxyphenol) benzotriazole of formula I, where R 1 is hydrogen atom, or a halogen atom, or a straight-chain or branched lower alkyl or lower alkoxy of 1 to 4 carbon atoms; R 2 is an unsubtituted or substituted aryl group or an unsubstituted or substituted straight-chain or branched alkyl having 1 to 18 carbon atoms or a cycloaliphatic group having 5 to 6 carbon atoms; and R 3 is a straight-chain or branched alkyl or alkylaryl group or alkoxyl or phenyl or phenyl substituted with alkyl, cycloalkyl, carboalkoxy, chlorine or arylalkyl groups.

  本发明涉及紫外线吸收化合物，它们的制备以及在涂料、塑料和局部应用产品中作为保护剂和稳定剂的用途。该化合物是式I中的2-(2-羟基苯基)苯并三唑的酮衍生物，其中R1是氢原子、卤素原子、1至4个碳原子的直链或支链低级烷基或低级烷氧基；R2是未取代或取代的芳基基团或未取代或取代的1至18个碳原子的直链或支链烷基或5至6个碳原子的环烷基团；R3是直链或支链烷基或烷基芳基基团或烷氧基或苯基或被烷基、环烷基、羧基烷氧基、氯或芳基烷基基团取代的苯基。
• Organic solvent-free process for the preparation of 2-(2-nitrophenylazo)phenols
  申请人：Pastor Daniel Stephen

  公开号：US20050053562A1

  公开（公告）日：2005-03-10

  Provided is a novel one-pot, organic solvent-free process for the preparation of 2-(2-nitrophenylazo) substituted phenols. The 2-(2-nitrophenylazo) substituted phenols are precursors for hydroxyphenylbenzotriazole UV absorbers.

  提供了一种新颖的一锅法，无机溶剂的制备2-(2-硝基苯偶氮基)取代酚的过程。这些2-(2-硝基苯偶氮基)取代酚是羟基苯并三唑紫外吸收剂的前体。
• COSMETIC EMULSION COMPOSITION
  申请人：ADEKA CORPORATION

  公开号：EP3603609A1

  公开（公告）日：2020-02-05

  An object of the present invention is to provide a cosmetic emulsion composition that satisfies all of the properties of usability, use sensation, and transparency in appearance. In order to achieve this object, the present invention provides a cosmetic emulsion composition that contains (A) a component containing a monoalkyl glyceryl ether having a C6-8 alkyl group and (B) a component containing an associative urethane.

  本发明的目的是提供一种化妆品乳液组合物，该组合物满足可用性、使用感和外观透明性的所有特性。为了实现这一目标，本发明提供了一种化妆品乳液组合物，它包含（A）一种含有具有 C6-8 烷基的单烷基甘油醚的成分和（B）一种含有缔合聚氨酯的成分。
• ONE-POT PROCESS FOR THE PREPARATION OF 5-SULFONYL-SUBSTITUTED BENZOTRIAZOLES
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1144391A1

  公开（公告）日：2001-10-17