1.10-phenanthroline hydrogennitrate | 80652-01-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1.10-phenanthroline hydrogennitrate
• CAS: 80652-01-3
• 化学式: C₁₂H₉N₂*NO₃
• 分子量: 243.222
• InChiKey: LJARTXPBMSWCTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.44
• 重原子数：
  18.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  89.15
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (n-Bu₄N)₂[Pt(NO₃)₆] 、 1.10-phenanthroline hydrogennitrate 以 水 、 乙腈 为溶剂， 以92%的产率得到(phenH)₄(NO₃)₂[Pt(NO₃)₆]
  参考文献：
  名称：

  Platinum(IV) Nitrato Complexes with 1,10-Phenanthroline

  摘要：

  The reaction between 1,10-phenanthroline (phen) and a nitric acid solution of platinum was studied. It was shown that, in contrast to the earlier studied reactions with pyridine and piperazine, no solid phases were formed by the salts of anionic platinum(IV) nitrato complexes with the phenanthrolinium cation in this case due to their high solubility. The new molecular platinum(IV) complex containing 1,10-phenanthroline [Pt(phen)(NO3)(4)] (1) was prepared upon long-term exposure. The salt (phenH)(4)(NO3)(2)[Pt(NO3)(6)] (2) was synthesized by the reaction between phenanthrolinium dinitrate (phen center dot 2HNO(3)) and the salt (Bu4N)(2)[Pt(NO3)(6)] in acetonitrile with a high yield. The crystal structure of complexes 1 and 2 was characterized by X-ray diffraction. Complex 2 was studied by IR spectroscopy, thermal analysis, and solid-state magic-angle spinning (SS-MAS) Pt-195 NMR spectroscopy. The results of this work could be used to develop the synthesis of new platinum complexes and for the preparation of platinum-containing heterogeneous catalysts.

  DOI：

  10.1134/s0036023620100216

文献信息

• Further studies of the hexaquo chromium(III) ion o-phenanthroline reaction
  作者：R.G. Inskeep、Merrill Benson

  DOI：10.1016/0022-1902(61)80278-9

  日期：1961.12

  Evidence is presented that cis diaquobis (o-phenanthroline) chronium(III) nitrate is more stable than the trans-diaquobis (o-phenanthroline) chromium(III) nitrate. Infra-red spectra from 5 to 40 μ are presented for cis-diaquobis (o-phenanthroline) chromium(III) nitrate and for the tetrakis (o-phenanthroline) μ-diol dichromium(III) nitrate as well as the pure ligand.

  有证据表明，顺式对二氮杂菲（邻-菲咯啉）硝酸铬（III）比反式对二氮杂菲（邻-菲咯啉）铬（III）稳定。给出了5–40μ的红外光谱，分别是顺式-双喹啉（邻-菲咯啉）硝酸铬（III）和四（邻-菲咯啉）μ-二醇硝酸二铬（III）以及纯配体。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cr: MVol.C, 48, page 107 - 109
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pb: MVol.C4, 185, page 1623 - 1625
  作者：

  DOI：——

  日期：——
• Biswas, A.; Mitra, T.; Sen, S., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Biswas, A.、Mitra, T.、Sen, S.

  DOI：——

  日期：——
• Pirtea, T. I.; Simon-Nicolau, J., 1962, vol. 11, p. 101 - 104
  作者：Pirtea, T. I.、Simon-Nicolau, J.

  DOI：——

  日期：——