| 74344-18-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并噻唑类
• CAS: 74344-18-6
• 化学式: C₃₆H₂₂N₄NiO₂S₂
• 分子量: 665.418
• InChiKey: KZSZROMORJQGTG-BPLVGVCGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  镍 、 N-(2-Hydroxy-1-naphthyl-methylen)-2-amino-benzthiazol 在 Na₂CO₃ 作用下， 以 乙醇 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERISATION OF THE NEW THIAZOLE SCHIFF BASE 2-(2-HYDROXY)NAPHTHYLIDENEAMINO-BENZOTHIAZOLE AND ITS COMPLEXES WITH Co(II), Cu(II), AND Ni(II) IONS

  摘要：

  The new ligand 2-(2-hydroxy)naphthylideneamitiobenzothiazole has been synthesised from 2-aminobenzothiazole and 2-hydroxynaphthylaldehyde by condensation in ethanol. Metal complexes of the ligand were prepared with chloride salts of Co(II), Cu(II), and Ni(II) in ethanol. The ligand and its complexes have been characterised by microanalyses, magnetic susceptibility, thermogravimetric analysis, FT-IR, C-13, H-1 NMR, and UV-Visible spectroscopy. From these findings, it is suggested that two ligands coordinate to each metal atom by hydroxyl and the imino nitrogen to form high-spin tetrahedral complexes with Co(II) and Ni(II) while forming diamagnetic binuclear complex with Cu(II).

  DOI：

  10.1081/sim-120003787