| 1391708-00-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 原羧酸衍生物
• CAS: 1391708-00-1
• 化学式: C₂₃H₃₇N₂*I
• 分子量: 468.465
• InChiKey: NEQKJLJNUZDJLI-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  1,3-di-(1-adamantyl)-1-cyanoamidine 在 calcium hydride 、 sodium ethanolate 作用下， 以 乙醇 、 乙腈 为溶剂， 反应 7.0h， 生成 1-methyl-1,3-di-(1-adamantyl)formamidinium hydroiodide 、
  参考文献：
  名称：

  A base induced transformation of a 1,3-dimethyl-1,3-di(1-adamantyl)formamidinium salt into β-[methyl-(1-adamantyl)amino]acrylonitriles in aliphatic nitriles

  摘要：

  A novel 1,3-dimethyl-1,3-di-(1-adamantyl)formamidinium perchlorate has been prepared via the Vilsmeier-Haack reaction of N-methyl-N-(1-adamantyl)formamide and N-methyl-N-(1-adamantyl) amine in a mixture of phosphorus oxychloride and benzene. The new formamidinium salt was found to undergo addition-elimination reactions when treated with sodium hydride in acetonitrile or propionitrile solution, thereby forming the corresponding beta-[methyl(1-adamantyl)amino]acrylonitriles and N-methyl-N-(1-adamantyl) amine. The H-1 and C-13 NMR spectra and the single-crystal X-ray structure of the new formamidinium salt have been determined along with those of the related compound 1,3-di-(1-adamantyl)-1-cyanoamidine and the corresponding beta-(dialkylamino)acrylonitriles.

  DOI：

  10.3998/ark.5550190.0013.207