[Mn(terephthalate)(1,10-phenanthroline)](n) | 375364-99-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Mn(terephthalate)(1,10-phenanthroline)](n)
• 英文别名: [Mn(tp)(phen)]n；Mn(1,4-benzenedicarboxylate)(1,10-phenantroline)；Mn(1,4-BDC)(1,10 Phen)
• CAS: 375364-99-1
• 化学式: C₈H₄O₄*C₁₂H₈N₂*Mn
• 分子量: 399.264
• InChiKey: ILGZLRCTMBVXQG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.19
• 重原子数：
  27.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  对苯二腈 、 1,10-菲罗啉 、 manganese(II) chloride tetrahydrate 以 水 为溶剂， 以57%的产率得到[Mn(terephthalate)(1,10-phenanthroline)](n)
  参考文献：
  名称：

  Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures

  摘要：

  1,4-二氰基苯、联苯和M(OAc)2（M = Co, Zn）或MCl2（M = Cu, Mn, Cd）的水热反应导致1,4-二氰基苯水解生成对苯二甲酸，并形成五种聚合物配合物[M(ta)(phen)(H2O)]n（M = Co, 1；Zn, 3）、[Cu(ta)(phen)]n（2）、[Mn(ta)(phen)]n（4）、[Cd(ta)1/2(phen)Cl]n（5）（ta = 对苯二甲酸盐，phen = 1,10-菲啰啉）。晶体结构分析表明，配合物1-3具有一维之字形链结构，而4和5具有具有通道的三维网络结构。对1、2和4的磁化率测量与通过ta桥出现弱反铁磁相互作用一致。

  DOI：

  10.1039/b102888j

文献信息

• Inorganic–organic hybrid compounds exhibiting both magnetic order and non-linear optical properties
  作者：H.S.S. Ramakrishna Matte、A.K. Cheetham、C.N.R. Rao

  DOI：10.1016/j.ssc.2009.03.033

  日期：2009.6

  Hybrid organic–inorganic framework compounds constitute an important class of materials whose properties, especially paired ones, have not been adequately investigated hitherto. In this communication, we report the non-linear optical properties of hybrid compounds exhibiting interesting magnetic properties.

  杂化有机-无机骨架化合物构成了一类重要的材料，其性质，尤其是配对材料，迄今尚未得到充分研究。在本次交流中，我们报告了具有有趣磁性的杂化化合物的非线性光学特性。
• Synthesis, crystal structure and photoelectric property of Mn(II/IV) coordination complexes
  作者：Li Zhang、Shu-Yun Niu、Jing Jin、Li-Ping Sun、Guang-Di Yang、Ling Ye

  DOI：10.1016/j.ica.2008.07.010

  日期：2009.4

  Three novel coordination complexes [Mn(tpha)(phen)](n) (1); [Mn(na)(2)(H2O)(2)](n) (2); [Mn(phen)(2) (OH)Cl] center dot Cl center dot (OH) center dot (C9H11NO2) center dot 2H(2)O} (3) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction (H(2)tpha = terephthalic acid, Hna = nicotinic acid, phen = 1,10-phenanthroline). The tpha groups in complex 1 bridge the Mn(II) ions to an infinite 3D framework. Complex 2 exhibits a 2D network structure in which the Mn(II) ions are linked by nicotinic groups. Complex 3 is connected to a 2D coordination supramolecule by hydrogen bonds. The results of surface photovoltage spectra (SPS) of complexes 1-3 indicate that they all exhibit positive surface photovoltage (SPV) responses in the range of 300-800 nm. However, the intensity, position and numbers of SPV responses are obviously different. The distinctions can be mainly attributed to their structures, valences and coordination environments of the manganese ions in the three complexes. Moreover the external. field induced surface photovoltage spectra (FISPS) of the three complexes have been measured. (C) 2008 Elsevier B. V. All rights reserved.
• Syntheses, crystal structures and magnetic behaviors of three MnII-terephthalate coordination polymers containing terminal ligands
  作者：Xiao-Ming Lu、Pei-Zhou Li、Xiu-Teng Wang、Song Gao、Xiao-Jun Wang、Shuo Wang、Yu-Heng Deng、Yong-Jun Zhang、Lei Zhou

  DOI：10.1016/j.poly.2008.04.029

  日期：2008.8

  Three Mn-II-terephthalate coordination polymers, Mn-II(tp)(bpy)(H2O)}, (1), Mn-3(II)(tp)(6/2)(bpy)(2) center dot (dmf)}(n) (2) and Mn-II(tp)(phen)}(n) (3) (tp = terephthalic dianion, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) have been synthesized and characterized by single crystal X-ray diffraction studies and low temperature (2-300 K) magnetic measurements. The structure analysis of 1-3 show that they all are coordination polymers composed of Mn atoms as nodes and terephthalate dianions as spacers. Interestingly, compound 1 consists of 1D infinite zigzag chains, while compound 2 consists of 2D sheets and compound 3 has a 3D framework structure. The study of the temperature dependent magnetic susceptibilities revealed that all of the polymers show antiferromagnetism. (C) 2008 Elsevier Ltd. All rights reserved.