tetramethyl deca-O-methylwoodfordinate | 103425-51-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 单宁
• 英文名称: tetramethyl deca-O-methylwoodfordinate
• 英文别名: Methyl 2-[2,3-dimethoxy-6-methoxycarbonyl-4-(2,3,4-trimethoxy-6-methoxycarbonylphenoxy)phenyl]-3,4-dimethoxy-5-(2,3,4-trimethoxy-6-methoxycarbonylphenoxy)benzoate
• CAS: 103425-51-0；147976-47-4
• 化学式: C₄₂H₄₆O₂₀
• 分子量: 870.815
• InChiKey: XRRWEEIMVIZYST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  62
• 可旋转键数：
  23
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  216
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 alkaline earth salt of/the/ methylsulfuric acid 在 sodium methylate 作用下， 生成 tetramethyl deca-O-methylwoodfordinate
  参考文献：
  名称：

  A phenolcarboxylic acid from the tannin substances of Chamaenerium angustifolium

  摘要：

  DOI：

  10.1007/bf00574595

文献信息

• Tannins and Related Polyphenols of Lythraceous Plants. Part2. Woodfordin D and Oenothein A, Trimeric Hydrolyzable Tannins of Macro-Ring Structure with Antitumor Activity.
  作者：Takashi YOSHIDA、Tong CHOU、Muneto MATSUDA、Taeko YASUHARA、Kazufumi YAZAKI、Tsutomu HATANO、Aya NITTA、Takuo OKUDA

  DOI：10.1248/cpb.39.1157

  日期：——

  trimeric hydrolyzable tannins, woodfordin D (5) and oenothein A (13), were isolated from the dried flowers of Woodfordia fruticosa, and their macrocyclic structures, which have a novel constituent unit (woodfordinoyl group) connecting the monomers, have been elucidated on the basis of spectral and chemical evidence. Oenothein A (13) was also isolated from the leaves of Oenothera biennis.

  从桔梗的干燥花中分离出两种新的抗肿瘤三聚体可水解单宁，伍德福德D（5）和卵磷脂A（13），它们的大环结构具有连接单体的新组成单元（伍德福德基）。根据光谱和化学证据进行了阐明。还从月见草的叶子中分离出Oenothein A（13）。
• A New Trimeric Hydrolyzable Tannin, Oenotherin T2, Isolated from Aerial Parts of Oenothera tetraptera Cav.
  作者：Tsutomu Hatano、Shoko Taniguchi、Yoko Imayoshi、Takashi Yoshida

  DOI：10.3987/com-08-s(d)26

  日期：——

  A new hydrolyzable tannin, oenotherin T-2, was isolated from the aerial parts of Oenothera tetraptera Cav., together with 15 known polyphenolic compounds. The trimeric structure of oenotherin T-2 was elucidated based on spectroscopic data and chemical correlation with oenotherin T-1.
• A macrocyclic ellagitannin trimer, oenotherin T1, from Oenothera species
  作者：Shoko Taniguchi、Yoko Imayoshi、Ryoko Yabu-uchi、Hideyuki Ito、Tsutomu Hatano、Takashi Yoshida

  DOI：10.1016/s0031-9422(01)00435-6

  日期：2002.1

  Oenotherin T-1 was isolated from leaves of Oenothera tetraptera as a major ellagitannin. Its structure, that of a macrocyclic trimer with a new acyl group, an isodehydrovaloneoyl group, was established. This compound was also produced by callus tissues induced from O. laciniata leaves. (C) 2002 Published by Elsevier Science Ltd.