N-phenyl-3-phenylnorbornadiene-2-carbaldehyde imine | 123316-35-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: N-phenyl-3-phenylnorbornadiene-2-carbaldehyde imine
• 英文别名: 3-phenylnorbornadiene-2-(N-phenyl)aldimine；N-phenyl-1-(3-phenyl-2-bicyclo[2.2.1]hepta-2,5-dienyl)methanimine
• CAS: 123316-35-8
• 化学式: C₂₀H₁₇N
• 分子量: 271.362
• InChiKey: RDVXTHZEFGUBLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-phenyl-3-phenylnorbornadiene-2-carbaldehyde imine 以 异丙醇 为溶剂， 生成 N-phenyl-1-(5-phenyl-1-tetracyclo[3.2.0.02,7.04,6]heptanyl)methanimine
  参考文献：
  名称：

  Photochromic Behaviour of 2,3-Substituted Norbornadiehes

  摘要：

  A series of novel 2,3-substituted norbornadienes has been prepared, Under UV- and Vis-irradiation in isopropanol and acetonitrile compounds undergo (2+2) valence isomerization into the corresponding quadricyclanes, the back interconversion being catalysed by CF3COOH or MoO3.

  DOI：

  10.1080/10587259408037804
• 作为产物：
  描述：

  N-phenyl-1-(5-phenyl-1-tetracyclo[3.2.0.02,7.04,6]heptanyl)methanimine 在 三氟乙酸 作用下， 以 甲苯 为溶剂， 生成 N-phenyl-3-phenylnorbornadiene-2-carbaldehyde imine
  参考文献：
  名称：

  Photochromic Behaviour of 2,3-Substituted Norbornadiehes

  摘要：

  A series of novel 2,3-substituted norbornadienes has been prepared, Under UV- and Vis-irradiation in isopropanol and acetonitrile compounds undergo (2+2) valence isomerization into the corresponding quadricyclanes, the back interconversion being catalysed by CF3COOH or MoO3.

  DOI：

  10.1080/10587259408037804

文献信息

• Photochemical properties and structures of substituted norbornadienes
  作者：S. M. Aldoshin、V. A. Bren、A. D. Dubonosov、O. A. Kozina、V. I. Minkin、V. A. Chernoivanov、I. I. Chuev

  DOI：10.1007/bf00702394

  日期：1995.3

  The spectral and photochemical properties of 3-phenylnorbomadiene-2-(N-phenyl) aldimine and 3-phenyl-2-(2,2-dicyanovinyl)narbornadiene have been studied, and their structures have been established by X-ray analysis. It was found that the C(2)=C(3) bonds in these compounds are longer than those in unsubstituted norbornadienes. It was established that long-wave absorbtion boundaries and quantum yields of the photoisomerization of 2,3-disubstituted norbornadienes to give the corresponding quadricyclanes increase as the C(2)=C(3) bond length increases and as the bond order decreases.
• Chernoivanov, V. A.; Dubonosov, A. D.; Minkin, V. I., Russian Journal of Organic Chemistry, 1989, vol. 25, # 2.2, p. 399 - 400
  作者：Chernoivanov, V. A.、Dubonosov, A. D.、Minkin, V. I.、Bren', V. A.、Lyubarskaya, A. E.

  DOI：——

  日期：——