申请人:SUMITOMO CHEMICAL COMPANY, LIMITED
公开号:EP0059958A1
公开(公告)日:1982-09-15
A process for producing polyphenylene oxide which comprises contacting a phenolic monomer with oxygen in the presence of a catalyst composed of a manganese (II) salt and an ortho-hydroxyazo compound represented by the following formula:
where A and B represent identical or different arylene ring having a valency of at least 2 and having an oxy group and an azo group directly linked to the ortho carbon atoms of the arylene ring and R represents hydrogen or lower alkyl group, or in the presence of said catalyst and an amine, in a polymerization solvent containing a base and thereby subjecting said phenolic monomer to an oxidative polymerization.
一种生产聚苯醚的工艺,它包括在由锰(II)盐和下式代表的邻羟基偶氮化合物组成的催化剂存在下,使酚类单体与氧气接触:
式中 A 和 B 代表相同或不同的芳烯环,其价数至少为 2,并有一个氧基和一个偶氮基直接连接到芳烯环的正碳原子上,R 代表氢或低级烷基,或在所述催化剂和胺的存在下,在含有碱的聚合溶剂中,使所述酚类单体进行氧化聚合。