[Cu((S,S)-(Cl2C6H2OCHN(C10H6)2(OH)))2] | 443286-76-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Cu((S,S)-(Cl2C6H2OCHN(C10H6)2(OH)))2]
• CAS: 443286-76-8；792900-62-0
• 化学式: C₅₄H₃₂Cl₄CuN₂O₄
• 分子量: 978.217
• InChiKey: SPIXVMSYLOENTH-BNJGBMCFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(3,5-dichloro-2-hydroxybenzylideneamino)-2'-hydroxy-1,1'-binaphthyl 、 copper diacetate 以 甲醇 为溶剂， 以52%的产率得到[Cu((S,S)-(Cl2C6H2OCHN(C10H6)2(OH)))2]
  参考文献：
  名称：

  Ligand chirality-controlled selective formation of mono- and dinuclear copper complexes

  摘要：

  Reaction of copper(II) acetate with the (S)-enantiomer of a tridentate binaphthyl Schiff base ligand. 2-(3,5-dichloro-2-hydroxybenzylideneamino)-2'-hydroxy-1,1'-binaphthyl (H2L), in methanol afforded mononuclear copper(II) complex [Cu-2(II)(HL)(2)] ((S,S)-1) in 52% isolated yield. The same reaction gave dinuclear copper(II) complex [Cu-2(II)(L)(2)] ((R,S)-2) in 73% isolated yield when racemic-H2L was used instead of (S)-H2L. Both complexes (S,S)-1 and (R,S)-2 were characterized by elemental analysis, mass spectrometry, and X-ray crystallography. The present work highlights the functioning of ligand chirality as a 'switch' for selective formation of mono- and dinuclear metal complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00806-4