1-naphthalen-1-yl-N-[4-[[2,4,6-trimethyl-3,5-bis[[4-(naphthalen-1-ylmethylideneamino)phenoxy]methyl]phenyl]methoxy]phenyl]methanimine | 1419639-49-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-naphthalen-1-yl-N-[4-[[2,4,6-trimethyl-3,5-bis[[4-(naphthalen-1-ylmethylideneamino)phenoxy]methyl]phenyl]methoxy]phenyl]methanimine
• CAS: 1419639-49-8
• 化学式: C₆₃H₅₁N₃O₃
• 分子量: 898.116
• InChiKey: CHSCGZXCGQIIEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.1
• 重原子数：
  69
• 可旋转键数：
  15
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  64.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4,4',4"-(((2,4,6-Trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))trianiline 、 1-萘甲醛 以 甲醇 为溶剂， 以76%的产率得到1-naphthalen-1-yl-N-[4-[[2,4,6-trimethyl-3,5-bis[[4-(naphthalen-1-ylmethylideneamino)phenoxy]methyl]phenyl]methoxy]phenyl]methanimine
  参考文献：
  名称：

  Selective fluorescence sensor for Al3+ and Pb2+ in physiological condition by a benzene based tripodal receptor

  摘要：

  We have synthesized a benzene based tripodal receptor containing naphthalene motifs as signaling unit. The receptor can selectively bind Al3+/Pb2+ metal ions with a significant change in its fluorescence and UV/Vis spectra, while the addition of other metal ions (Na+, K+, Ca2+, Mg2+, Cr3+, Hg-2, Cu2+, Zn2+, Fe2+, Co2+, Ni2+, Cd2+, and Ag+) produces insignificant or minor changes. The formation of receptor-metal ion complex is also proved by NMR and mass spectroscopic analysis. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.114