| 355857-03-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 355857-03-3
• 化学式: C₁₂H₃₉P₄ReS₂
• 分子量: 557.676
• InChiKey: OFUSHYCEALDOOZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.62
• 重原子数：
  19.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  、 1,2-双(二甲基瞵)乙烷 以 乙腈 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  [ReH(SH)2(PMe3)4]: A Catalyst for Fundamental Transformations Involving H2 and H2S

  摘要：

  Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH) and hydridic (ReH) sites; these sites communicate by an intramolecular exchange process (see scheme; X=OMe, SH).

  DOI：

  10.1002/1521-3773(20010618)40:12<2351::aid-anie2351>3.0.co;2-l
• 作为产物：
  描述：

  tetraethylammonium tetrathioperrhenate 、 硫化氢 、 三甲基膦 以 乙腈 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  [ReH(SH)2(PMe3)4]: A Catalyst for Fundamental Transformations Involving H2 and H2S

  摘要：

  Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH) and hydridic (ReH) sites; these sites communicate by an intramolecular exchange process (see scheme; X=OMe, SH).

  DOI：

  10.1002/1521-3773(20010618)40:12<2351::aid-anie2351>3.0.co;2-l
• 作为试剂：
  描述：

  硫化氢 、 氘 在 ReH(SH)2(P(CH₃)3)4 作用下， 以 氘代苯 为溶剂， 生成 硫化氢-D1 、 氢气 、 氢化氘
  参考文献：
  名称：

  [ReH(SH)2(PMe3)4]: A Catalyst for Fundamental Transformations Involving H2 and H2S

  摘要：

  Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH) and hydridic (ReH) sites; these sites communicate by an intramolecular exchange process (see scheme; X=OMe, SH).

  DOI：

  10.1002/1521-3773(20010618)40:12<2351::aid-anie2351>3.0.co;2-l