(η6-p-cymene)Ru(II)Cl(OC6H4-2-CH2NHC6H4-naphthyl) | 388110-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (η6-p-cymene)Ru(II)Cl(OC6H4-2-CH2NHC6H4-naphthyl)
• 英文别名: chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene;2-[(naphthalen-1-ylamino)methyl]phenolate
• CAS: 388110-64-3
• 化学式: C₂₇H₂₈ClNORu
• 分子量: 519.048
• InChiKey: HQKSDBCOHUISFS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.33
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  35.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 2-(Naphthalen-1-ylaminomethyl)-phenol 在 Na₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 生成 (η6-p-cymene)Ru(II)Cl(OC6H4-2-CH2NHC6H4-naphthyl)
  参考文献：
  名称：

  Transfer hydrogenation of acetophenone promoted by (arene)ruthenium(II) reduced Schiff base complexes: an X-ray structure of [(η6-p-cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)]

  摘要：

  Arene ruthenium(II) reduced Schiff base complexes of formulation [(eta (6)-p-cymene)RuCl(L-n)] (1-5, n = 1-5) were prepared by reacting [(eta (6)-p-cymene)RuCl2](2) with HLn in the presence of sodium carbonate in CH2Cl2. The complexes contain an eta (6)-p-cymene group, a chloride and a bidentate chelating N,O-donor ligand. The molecular structure of [(eta (6)-p-cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)] (1) has been determined by X-ray crystallography. The complexes are found to be catalytically active for transfer hydrogenation of acetophenone to (+/- )1-phenylethanol in the presence of KOH and isopropanol showing percent conversion of 98 with the catalysts having a bulky substituent adjacent to the O- and N-donor sites of the auxiliary ligand. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(01)00894-4