octa(5,5-dimethyl-O,O-1,3-propylenephosphate)-2,2-bis(3-hydroxy-2,2-bishydroxymethylpropoxymethyl)propane-1,3-diol | 1186366-76-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: octa(5,5-dimethyl-O,O-1,3-propylenephosphate)-2,2-bis(3-hydroxy-2,2-bishydroxymethylpropoxymethyl)propane-1,3-diol
• CAS: 1186366-76-6
• 化学式: C₅₅H₁₀₄O₂₆P₈S₈
• 分子量: 1685.73
• InChiKey: JIKCQCPHBGAQMY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  octa(5,5-dimethyl-O,O-1,3-propylenephosphite)-2,2-bis(3-hydroxy-2,2-bis-hydroxymethylpropoxymethyl)propane-1,3-diol 在 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 5.0h， 以75%的产率得到octa(5,5-dimethyl-O,O-1,3-propylenephosphate)-2,2-bis(3-hydroxy-2,2-bishydroxymethylpropoxymethyl)propane-1,3-diol
  参考文献：
  名称：

  Pioneering examples of preparative phosphorylation of pentaerythritol

  摘要：

  The transacetalization of dimethoxyethane with tripcntaerythritol affords respective trimethylene diol. The oligools derived from the tripentaerytritol and its trimethylene derivative were used in the syntheses of unusual oligophosphites that might be interesting as ligands for intricate metal complex constructions.

  DOI：

  10.1134/s1070363208080070