| 481635-47-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• CAS: 481635-47-6
• 化学式: C₁₄H₈N₆O₂*Ni
• 分子量: 350.947
• InChiKey: ZQCFWOSQXJQYSY-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 1,10-phenanthrolino-(5,6-b)-2,3-dihydroxyimino-(1,4)-diazin 在 NaOH 作用下， 以 乙醇 为溶剂， 以57.4%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF 5,6-DIAMINO-1,10-PHENANTHROLINE SUBSTITUTEDANTI-DICHLOROGLYOXIME AND ITS COMPLEXES WITH COBALT(II), NICKEL(II), AND COPPER(II)

  摘要：

  In this study, a new dioxime ligand, 1,10-phenanthrolino(5,6-b)-2,3-dihydyroxyimino-1,4-diazin was synthesized from the reaction of 5,6-diamino-1,10-phenanthroline with antidichloroglyoxime. Polymeric complexes with Ni(II), Co(II) and Cu(II) have been obtained. The new compounds have been characterized by FTIR, H-1 NMR (DMSO-d(6)), elemental analyses and magnetic measurements. The ligand and the Ni(II), Co(II) and Cu(II) complexes have been studied potentiometrically. The metal to the ligand ratio of the Cu(II), Ni(II) and Co(II) complexes was found to be 1: 1. The Co(II), Ni(II) and Cu(II) complexes of the ligand are paramagnetic. Protonation constants of the ligand and overall formation constants of the complexes have been calculated from potentiometric data using the program TITFIT.

  DOI：

  10.1081/sim-120014855