trans-bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato-κN3)copper(II) | 854080-52-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: trans-bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato-κN3)copper(II)
• CAS: 854080-52-7
• 化学式: C₅₈H₅₂CuN₆O₄
• 分子量: 960.635
• InChiKey: VZYKWNPVEPSXOA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2-二苯基乙胺 、 copper diacetate 、 苯妥英 以 乙醇 为溶剂， 生成 trans-bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato-κN3)copper(II)
  参考文献：
  名称：

  trans-Bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato-κN³)copper(II) and its chloroform disolvate

  摘要：

  The crystal structures of the title compounds, [Cu(C15H11N2O2)(2)(C14H15N)(2)] and [Cu(C15H11N2O2)(2)(C14H15N)(2)]center dot 2CHCl(3), respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu-II atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.

  DOI：

  10.1107/s010827010500209x