| 37240-74-7

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• CAS: 37240-74-7
• 化学式: Kr₂
• 分子量: 167.6
• InChiKey: YZGLTWIGDHBSBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.0
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  盐酸 、 以 gaseous matrix 为溶剂， 生成 (hydrogen chloride)2
  参考文献：
  名称：

  在二元离子分子反应中生成二聚体离子M 2 +（MCH 4，H 2 O，COS，C 2 H 2，C 2 H 6，HCl，N 2 O和CO）

  摘要：

  先前对Kr 2 +和Xe 2 +离子与几种分子气体M的反应的研究表明，会生成KrM +和XeM +类型的离子。我们继续进行这些研究，并观察到后者离子在“转换”反应中与M迅速反应，生成M 2 +二聚体离子。因此形成二聚体离子，例如（CH 4）2 +和（H 2 O）2 +，这些在母体离子M +（例如CH 4 +和H 2 O +）及其母体分子M; 相反，这样的反应导致碎片产物（即CH 5 + + CH 3； H 3 O + + OH）。观察到的其他二聚体离子是（COS）2 +，（C 2 H 2）2 +，（C 2 H 6）2 +，（HCl）2 +，（N 2 O）2 +和（CO）2 +。对这些二聚离子中电荷的键合和位置进行了评论。

  DOI：

  10.1016/s0009-2614(89)87026-5
• 作为产物：
  描述：

  氪气 以 gas 为溶剂， 生成
  参考文献：
  名称：

  Gas phase atomic association reactions of Ar⁺, Kr⁺, and Xe⁺ at temperatures near 1 K

  摘要：

  We report the measurement of gas phase three-body atomic ion–atom association reaction rate coefficients at temperatures near 1 K using a free jet flow reactor. The association rate coefficients for the reactions of Ar+ with Ar and Ne, Kr+ with Kr and Ar, and the reactions of Xe+ with Xe, Kr, and Ar have been measured. In all these cases except Ar++Ne, the rate at 1 K is in excess of 9×10−29 cm3/s and a strong negative temperature dependence is observed. These observations are discussed with respect to several microscopic descriptions of the association process.

  DOI：

  10.1063/1.462520

文献信息

• Photodissociation of Kr⁺_<i>n</i>clusters
  作者：Z. Y. Chen、C. D. Cogley、J. H. Hendricks、B. D. May、A. W. Castleman

  DOI：10.1063/1.458854

  日期：1990.9

  The photodissociation of Kr+n (3≤n≤11) cluster ions is observed for the first time in the 565 to 630 nm wavelength range. Kr+3 has a photodissociation cross section of (8.1±0.8)×10−17 cm2 at 612 nm, while Kr+4 and Kr+5 are found to have larger photodissociation cross sections than Kr+3 with a slightly red-shifted spectrum. Only Kr+ is detected as a photofragment of Kr+3, while in the Kr+n (4≤n≤7) experiments, both Kr+2 and Kr+ photofragments are seen. As size n increases from 7 to 11, Kr+ disappears and Kr+3 appears. Laser power studies show that all are single photon photodissociation processes. For higher order Kr+n clusters (4≤n≤7) the intensity ratio between the two photodissociation products Kr+2 and Kr+ is dependent on the wavelength of the laser light used in the photodissociation, but independent of the polarization direction of the laser. Translational energy analysis of the photofragments is used to investigate the photodissociation mechanisms. In contrast to the photodissociation of Kr+3, where two types of Kr+ photofragments with different values of translational energy release are observed, only one type of Kr+2 photofragment, with zero kinetic energy release is found in the Kr+4 photodissociation. These findings are discussed in terms of the dynamics of photodissociation and possible structures of these cluster ions.
• Bogdanova, I. P.; Vladimirov, V. A.; Marusin, V. D., Optics and Spectroscopy, 1989, vol. 66, p. 142 - 144
  作者：Bogdanova, I. P.、Vladimirov, V. A.、Marusin, V. D.、Yakovleva, V. I.

  DOI：——

  日期：——