Tripentaerythrit-triformal | 84808-77-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: Tripentaerythrit-triformal
• 英文别名: 2',2'':6',6'':10',10''-tri-O-methylene-2,2,6,6,10,10-hexakis(hydroxymethyl)-4,8-dioxa-1,11-undecane-diol；5,5-bis-[(5-hydroxymethyl-[1,3]dioxan-5-ylmethoxy)-methyl]-[1,3]dioxane；5,5-Bis-[(5-hydroxymethyl-[1,3]dioxan-5-ylmethoxy)-methyl]-[1,3]dioxan；[5-[[5-[[5-(hydroxymethyl)-1,3-dioxan-5-yl]methoxymethyl]-1,3-dioxan-5-yl]methoxymethyl]-1,3-dioxan-5-yl]methanol
• CAS: 84808-77-5
• 化学式: C₁₈H₃₂O₁₀
• 分子量: 408.446
• InChiKey: PYMYPIAVPUBKDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.02
• 重原子数：
  28.0
• 可旋转键数：
  10.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  114.3
• 氢给体数：
  2.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  Tripentaerythrit-triformal 在 吡啶 、 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 16.5h， 生成 2,2'-(((((((1,3-dioxane-5,5-diyl)bis(methylene))bis(oxy))bis(methylene))bis(1,3-dioxane-5,5-diyl))bis(methylene))bis(oxy))bis(1,3,2-dioxaphosphinane 2-sulfide)
  参考文献：
  名称：

  Bisthiophosphocholines of new type

  摘要：

  The synthesis of dithionophosphohomocholines was carried out by alkylation of trimethylamine with phosphorinane trimethylene derivatives of tripentaerithritols. As a source tripentaerithritol acetals besides the compounds of symmetric structure were used their stereoisomers.

  DOI：

  10.1134/s1070363211080044
• 作为产物：
  描述：

  三季戊四醇 在 盐酸 、 聚合甲醛 作用下， 生成 Tripentaerythrit-triformal
  参考文献：
  名称：

  Mixed esters of polyhydric alcohols

  摘要：

  公开号：

  US02441555A1

文献信息

• Pioneering examples of preparative phosphorylation of pentaerythritol
  作者：D. A. Predvoditelev、M. A. Malenkovskaya、O. V. V’yunskovskaya、E. E. Nifant’ev

  DOI：10.1134/s1070363208080070

  日期：2008.8

  The transacetalization of dimethoxyethane with tripcntaerythritol affords respective trimethylene diol. The oligools derived from the tripentaerytritol and its trimethylene derivative were used in the syntheses of unusual oligophosphites that might be interesting as ligands for intricate metal complex constructions.
• New data in the chemistry of phosphotrimethylenepentaerythritol
  作者：D. A. Predvoditelev、M. A. Malenkovskaya、O. V. V’yunskovskaya、E. E. Nifant’ev

  DOI：10.1134/s1070363209120093

  日期：2009.12

  Unsymmetrical trimethylene diol was obtained at the transacetalation of dimethoxymethane with tripentaerytritol. On the basis of the diol a group of acyclic and cyclic phosphites interesting as ligands for the metallocomplex bioregulators with sophisticated structure were synthesized.
• Werle, Peter; Nonnenmacher, Gerhard, Liebigs Annalen der Chemie, 1983, # 1, p. 150 - 153
  作者：Werle, Peter、Nonnenmacher, Gerhard

  DOI：——

  日期：——
• WERLE, P.;NONNENMACHER, G., LIEBIGS ANN. CHEM., 1983, N 1, 150-153
  作者：WERLE, P.、NONNENMACHER, G.

  DOI：——

  日期：——