(5aS,9S)-1-Heptyl-3-hydroxy-9-hydroxymethyl-5a-methyl-5a,7,9,10-tetrahydro-5,8-dioxa-acephenanthrylene-4,6-dione | 427899-65-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: (5aS,9S)-1-Heptyl-3-hydroxy-9-hydroxymethyl-5a-methyl-5a,7,9,10-tetrahydro-5,8-dioxa-acephenanthrylene-4,6-dione
• CAS: 427899-65-8
• 化学式: C₂₃H₂₈O₆
• 分子量: 400.472
• InChiKey: BPEPNAFOZUCWHB-PSLXWICFSA-N

反应信息

• 作为反应物：
  描述：

  (5aS,9S)-1-Heptyl-3-hydroxy-9-hydroxymethyl-5a-methyl-5a,7,9,10-tetrahydro-5,8-dioxa-acephenanthrylene-4,6-dione 在 甲醇 、 硫酸 、 锌 作用下， 反应 0.5h， 生成 (S)-5-Heptyl-10-hydroxy-3-hydroxymethyl-9-methyl-1,3,4,5,6,8-hexahydro-2-oxa-phenanthren-7-one
  参考文献：
  名称：

  Structure and absolute configuration of acetosellin, a new polyketide from a phytotoxic strain of Cercosporella acetosella

  摘要：

  A new yellow pigment, designated acetosellin 1, was isolated from the mycelium of Cercosporella acetosella as a reduced azaphilone metabolite. The structure of I was determined by spectroscopic investigations and chemical evidence. Compound I possesses a novel carbon skeleton that of a naphtopyrane derivative, linked to an extensively conjugated chain. The absolute configuration was determined by NOE experiments and CD correlations. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)00091-6
• 作为产物：
  描述：

  acetosellin 在 palladium on activated charcoal 氢气 作用下， 生成 (5aS,9S)-1-Heptyl-3-hydroxy-9-hydroxymethyl-5a-methyl-5a,7,9,10-tetrahydro-5,8-dioxa-acephenanthrylene-4,6-dione
  参考文献：
  名称：

  Structure and absolute configuration of acetosellin, a new polyketide from a phytotoxic strain of Cercosporella acetosella

  摘要：

  A new yellow pigment, designated acetosellin 1, was isolated from the mycelium of Cercosporella acetosella as a reduced azaphilone metabolite. The structure of I was determined by spectroscopic investigations and chemical evidence. Compound I possesses a novel carbon skeleton that of a naphtopyrane derivative, linked to an extensively conjugated chain. The absolute configuration was determined by NOE experiments and CD correlations. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)00091-6