trans-[Fe(II)(CN)4(DMSO)2](2-) | 877758-32-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: trans-[Fe(II)(CN)4(DMSO)2](2-)
• CAS: 877758-32-2
• 化学式: C₈H₁₂FeN₄O₂S₂
• 分子量: 316.188
• InChiKey: ZAEBHQKGXZRCSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Fe(II)(CN)4(DMSO)2](2-) 、 一氧化碳 以 二甲基亚砜 为溶剂， 生成 trans-[Fe(II)(CN)4(CO)2](2-)
  参考文献：
  名称：

  Further Study of the Reaction of Fe²⁺ with CN^-:  Synthesis and Characterization of cis and trans [Fe^II,III(CN)₄L₂]^n- Complexes

  摘要：

  The reaction of Fe2+ with CN-, which was first performed in 1704, has been used to synthesize a new series of basic [FeII,III(CN)4L2]n- complexes, where L is a monodentate ligand. trans-Na2[FeII(CN)4(DMSO)2] and cis-[NEt4]2[FeII(CN)4(pyridine)2] are synthesized by the direct reaction of FeCl2 with 4 equiv of CN- in DMSO or pyridine. Air oxidation of the latter compound gives cis-[NEt4][FeIII(CN)4(pyridine)2]. The non-cyanide ligands in these complexes undergo facile ligand exchange reactions with solvent. Reaction of cis-[NEt4]2[FeII(CN)4(pyridine)2] with CO at room temperature gives trans-[NEt4]2[FeII(CN)4(pyridine)(CO)].

  DOI：

  10.1021/ja0571951