tetranitrato(2,3,6,7,12,13,16,17-octamethyl-1,4,5,8,11,14,15,18-octaazacycloeicosane-1,3,5,7,11,13,15,17-octaene) dizinc(II) | 165287-08-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: tetranitrato(2,3,6,7,12,13,16,17-octamethyl-1,4,5,8,11,14,15,18-octaazacycloeicosane-1,3,5,7,11,13,15,17-octaene) dizinc(II)
• CAS: 165287-08-1
• 化学式: C₂₀H₃₂N₁₂O₁₂Zn₂
• 分子量: 763.327
• InChiKey: AGLWNASVQKWBKO-KCQSIROLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 3,6-dimethyl-4,5-diazaocta-3,5-diene-2,7-dione 、 乙二胺 以 甲醇 为溶剂， 以35%的产率得到tetranitrato(2,3,6,7,12,13,16,17-octamethyl-1,4,5,8,11,14,15,18-octaazacycloeicosane-1,3,5,7,11,13,15,17-octaene) dizinc(II)
  参考文献：
  名称：

  Transition metal complexes of 20–22-membered octaazamacrocycles: Synthesis and characterization

  摘要：

  A series of binuclear octaazamacrocyclic complexes [M(2)L(1)X(4)]-[M(2)L(2)X(4)] (M = Ni-II, Co-II and Zn-II;X = Cl or NO3) and [Cu(2)L(1)]X(4)-[Cu(2)L(2)]X(4) (X = Cl or NO3) have been synthesized by template condensation reaction of aliphatic primary diamines with 3,6-dimethyl-4,5-diazaocta-3,5-diene-2,7-dione in methanol. The overall geometry and stereochemistry of these complexes have been elucidated by IR, H-1 NMR, EPR and electronic spectral studies, and magnetic susceptibility and conductance values. An octahedral geometry around the metal ion is suggested for nickel, cobalt and zinc complexes, whilst a square planar geometry is proposed for copper complexes.

  DOI：

  10.1016/0277-5387(94)00395-u