Triethylammonium perfluorohexane sulfonate | 72033-41-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Triethylammonium perfluorohexane sulfonate
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonate;triethylazanium
• CAS: 72033-41-1
• 化学式: C12H16F13NO3S
• 分子量: 501.31
• InChiKey: UZCCMCYUIFRHDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.16
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70
• 氢给体数：
  1
• 氢受体数：
  16

文献信息

• Proton-conducting membrane and the use of the same
  申请人：Calundann Gordon

  公开号：US20050053820A1

  公开（公告）日：2005-03-10

  The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.

  本发明涉及一种基于多唑的新型质子传导聚合物膜，该膜具有优异的化学和热性能，可用于多种用途，尤其可用作聚合物电解质膜（PEM），用于生产 PEM 燃料电池的膜电极单元。
• Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells
  申请人：Kiefer Joachim

  公开号：US20050118478A1

  公开（公告）日：2005-06-02

  The present invention relates to a proton-conducting polymer membrane which is based on polyvinylsulphonic acid and is obtainable by a process comprising the steps A) mixing of a polymer with vinyl-containing sulphonic acid, B) formation of a flat structure using the mixture from step A) on a support, C) polymerization of the vinylsulphonic acid present in the flat structure from step B). Owing to its excellent chemical and thermal properties, a membrane according to the invention can be used in a wide variety of applications and is particularly useful as polymer electrolyte membrane (PEM) in PEM fuel cells.

  本发明涉及一种基于聚乙烯磺酸的质子传导聚合物膜，可通过以下步骤获得：A) 将聚合物与含乙烯基的磺酸混合；B) 利用步骤 A 的混合物在支架上形成平面结构；C) 对步骤 B 的平面结构中的乙烯基磺酸进行聚合。）由于本发明的膜具有优异的化学和热性能，可广泛应用于各种领域，尤其适用于 PEM 燃料电池中的聚合物电解质膜（PEM）。
• Proton-conducting polymer membrane comprising polymers containing phosphonic acid groups and its use in fuel cells
  申请人：Kiefer Joachim

  公开号：US20050244694A1

  公开（公告）日：2005-11-03

  The present invention relates to a proton-conducting polymer membrane comprising polymers containing phosphonic acid groups which is obtainable by a process comprising the steps A) mixing of vinyl-containing phosphonic acid with one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof which contain at least two acid groups per carboxylic acid monomer, and/or mixing of vinyl-containing phosphonic acid with one or more aromatic and/or heteroaromatic diamino carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof, B) heating of the mixture obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) polymerization of the vinyl-containing phosphonic acid present in the sheet-like structure obtainable according to step C).

  本发明涉及一种质子传导聚合物膜，该膜由含有膦酸基团的聚合物组成，可通过包括以下步骤的工艺获得 A) 将含乙烯基的膦酸与一种或多种芳香族四氨基化合物和一种或多种芳香族羧酸、其酯类、其酸卤化物或其酸酐混合，每个羧酸单体至少含有两个酸基，和/或将含乙烯基的膦酸与一种或多种芳香族和/或杂芳香族化合物混合、和/或将含乙烯基的膦酸与一种或多种芳香族和/或杂芳族二氨基羧酸、其酯、其酸卤化物或其酸酐混合。C) 将步骤 A) 和/或 B) 中的混合物涂抹在支撑物上，形成一层； D) 将步骤 C) 中得到的片状结构中的含乙烯基的膦酸聚合。
• Proton conducting polymer membrane comprising phoshphonic acid groups containing polyazoles and the use thereof in fuel cells
  申请人：Uensal Oemer

  公开号：US20060008690A1

  公开（公告）日：2006-01-12

  The present invention relates to proton-conducting polymer membranes which comprise polyazoles containing phosphonic acid groups and are obtainable by a process comprising the steps A) mixing of one or more aromatic and/or heteroaromatic tetraamino compounds with one or more aromatic and/or heteroaromatic carboxylic acids or derivatives thereof which contain at least two acid groups per carboxylic acid monomer, with at least part of the tetraamino compounds and/or the carboxylic acids comprising at least one phosphonic acid group, or mixing of one or more aromatic and/or heteroaromatic diaminocarboxylic acids, of which at least part comprises phosphonic acid groups, in polyphosphoric acid to form a solution and/or dispersion, B) heating of the solution and/or dispersion obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting.

  本发明涉及质子传导聚合物膜，该膜由含有膦酸基团的聚唑组成，可通过以下工艺获得 A) 将一种或多种芳香族和/或杂芳香族四氨基化合物与一种或多种芳香族和/或杂芳香族羧酸或其衍生物（每个羧酸单体至少含有两个酸基）混合、四氨基化合物和/或羧酸中至少有一部分含有至少一个膦酸基，或将一种或多种芳香族和/或杂芳族二氨基羧酸（其中至少有一部分含有膦酸基）混入多磷酸中，形成溶液和/或分散液， B) 在惰性气体中加热根据步骤 A) 得到的溶液和/或分散液，温度最高可达 350° C.C) 将步骤 A) 和/或 B) 中的混合物涂抹在支撑物上，形成一层膜； D) 处理步骤 C) 中形成的膜，直至其具有自支撑性。
• Proton-conducting membrane and use thereof verwendung
  申请人：Calundann Gordon

  公开号：US20060035095A1

  公开（公告）日：2006-02-16

  The present invention relates to novel polyazoles, a proton-conducting polymer membrane based on these polyazoles and its use as polymer electrolyte membrane (PEM) for producing membrane-electrode units for PEM-fuel cells, and also other shaped bodies comprising such polyazoles.

  本发明涉及新型多聚唑、基于这些多聚唑的质子传导聚合物膜及其作为聚合物电解质膜（PEM）的用途，用于生产 PEM 燃料电池的膜电极单元，以及由这些多聚唑组成的其他异型体。