[5-(cyclopenta-2,4-dien-1-ylmethoxymethyl)cyclopenta-1,3-dien-1-yl]-trimethylsilane;iron(2+) | 214218-54-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [5-(cyclopenta-2,4-dien-1-ylmethoxymethyl)cyclopenta-1,3-dien-1-yl]-trimethylsilane;iron(2+)
• CAS: 214218-54-9；182307-40-0
• 化学式: C₁₅H₂₀FeOSi
• 分子量: 300.256
• InChiKey: GEULIZXZNNBAJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopenta-2,4-dien-1-ylmethanol;iron(2+);(2-trimethylsilylcyclopenta-2,4-dien-1-yl)methanol 在 molecular sieves 4Å 、 tosyl chloride 作用下， 以 苯 为溶剂， 以68%的产率得到[5-(cyclopenta-2,4-dien-1-ylmethoxymethyl)cyclopenta-1,3-dien-1-yl]-trimethylsilane;iron(2+)
  参考文献：
  名称：

  Mono and difunctionalisation of chiral ferrocenyl bis-acetals. X-Ray crystal structure of bis-1,1′-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene

  摘要：

  The chiral 1,1'-bis-acetals, bis-1,1'-[(2S, 4S)-(hydroxymethyl)-2-dioxanel,3]-ferrocene (3) and 1,1'-bis-1,1'-[(2S, 4S)-(methoxymethyl)-2-dioxanel,3]-ferrocene (4) were synthesized. (3) was crystallographically characterised. The ortholithiation of (4) was studied in various conditions. Fair yields of monosubstituted compounds could be obtained with a complete regioselectivity in favor of the 2 position but the diastereoselectivities were moderate (up to 35%). Some disubstituted compounds can be isolated but in low yields (up to 8%). The regioselectivity is complete in favor of the 2,2'-disubstituted isomer. Only the diastereoisomer with two opposite planar chiralities is observed. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00449-5

文献信息

• Iftime, Gabriel; Daran, Jean-Claude; Manoury, Eric, Organometallics, 1996, vol. 15, p. 4808 - 4815
  作者：Iftime, Gabriel、Daran, Jean-Claude、Manoury, Eric、Balavoine, Gilbert G. A.

  DOI：——

  日期：——