(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-bis-(4-(2-naphthyl)phenyl)-amine | 1160294-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-bis-(4-(2-naphthyl)phenyl)-amine
• 英文别名: 4-naphthalen-2-yl-N-(4-naphthalen-2-ylphenyl)-N-[4-(9-phenylcarbazol-3-yl)phenyl]aniline
• CAS: 1160294-89-2
• 化学式: C₅₆H₃₈N₂
• 分子量: 738.931
• InChiKey: BWIIOOUBHUIGHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  58
• 可旋转键数：
  7
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 、 bis-(4-(2-naphthyl)phenyl)-(4-bromo-phenyl)-amine 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 14.0h， 以95%的产率得到(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-bis-(4-(2-naphthyl)phenyl)-amine
  参考文献：
  名称：

  [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  [FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE

  摘要：

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。

  公开号：

  WO2009072587A1

文献信息

• Carbazole Derivative, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using Carbazole Derivative
  申请人：Nomura Hiroko

  公开号：US20090160323A1

  公开（公告）日：2009-06-25

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α 1 , α 2 , α 3 , and α 4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar 1 and Ar 2 each represent an aryl group having less than or equal to 13 carbon atoms; R 1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R 2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供具有高发光效率的发光元件，并提供低功耗、低电压驱动的发光装置和电子装置，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3和α4各代表具有小于或等于13个碳原子的芳烃基；Ar1和Ar2各代表具有小于或等于13个碳原子的芳基；R1代表氢原子、具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种；R2代表具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种。此外，l、m和n各自独立地为0或1。
• Carbazole derivative, and light-emitting element, light-emitting device, and electronic device uing carbazole derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP2757094A1

  公开（公告）日：2014-07-23

  The present invention provides a novel carbazole derivative which may be used for the production of a light-emitting element having high luminous efficiency, and for the manufacture of light-emitting devices and electronic devices which consume low power and are driven at low voltage.

  本发明提供了一种新型咔唑衍生物，可用于生产具有高发光效率的发光元件，以及制造低功耗、低电压驱动的发光器件和电子设备。
• Carbazole derivative, and light-emitting element, light-emitting device, and electronic device using the carbazole derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10556864B2

  公开（公告）日：2020-02-11

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供一种具有高发光效率的发光元件，并提供一种低功耗和低电压驱动的发光器件和电子器件，提供了一种由通式（1）表示的咔唑衍生物。式中，α1、α2、α3 和 α4 分别代表具有小于或等于 13 个碳原子的芳基；Ar1 和 Ar2 分别代表具有小于或等于 13 个碳原子的芳基；R1 代表氢原子、具有 1 至 6 个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任一种；以及 R2 代表具有 1 至 6 个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任一种。此外，l、m 和 n 各自独立地为 0 或 1。
• CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  申请人：Semiconductor Energy Laboratory Co, Ltd.

  公开号：EP2225204A1

  公开（公告）日：2010-09-08
• ORGANIC EL DEVICE
  申请人：Endo Jun

  公开号：US20100219404A1

  公开（公告）日：2010-09-02

  An organic EL device includes: an anode, a cathode and an organic thin-film layer interposed between the anode and the cathode, in which the organic thin-film layer includes: an emitting layer containing a host material and a phosphorescent material; and a hole transporting layer provided adjacent to the anode relative to the emitting layer. The hole transporting layer includes a first hole transporting layer and a second hole transporting layer that are sequentially layered on the anode, in which the first hole transporting layer contains an amino compound substituted by an aromatic substituent represented by a formula (1) below and the second hole transporting layer contains at least one of compounds represented by formulae (2) to (5) below.