| 1416178-82-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1416178-82-9
• 化学式: C₂H₃O₂*C₁₂H₁₁CuN₄O₃S₂*H₂O
• 分子量: 463.982
• InChiKey: DXFUVPNUAMFYPT-ACQMDWLESA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (E)-1-((1,3,4-thiadiazol-2-yl)diazenyl)naphthalen-2-ol 、 copper diacetate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Cu(II) complexes of monobasic bi- or tridentate (NO, NNO) azo dye ligands: Synthesis, characterization, and interaction with Cu-nanoparticles

  摘要：

  A series of copper(II) azo complexes having the formula [CuL1-4(nH(2)O)]center dot OAc center dot xH(2)O where (n = 1-2) and (x = 0-1) have been synthesized using azo dyes containing the triazol and thiadiazole moieties. The azodyes and their metal complexes were characterized by elemental analysis, molar conductance, IR, electronic, mass, ESR spectra, magnetic moment measurements, and thermal analyses. IR spectra showed that the ligands having triazole moiety were coordinated with the copper(II) ion in a tridentate manner with ONN donor sites of the naphthyl OH, N-atoms of azo group, and triazole moiety while azodyes having thiadiazole moiety were coordinated with the copper(II) ion in a bidentate manner with ON donor sites of the naphthyl OH and the N-atom of the group. The thermodynamic activation parameters such as Delta E*, Delta H*, Delta S*, and Delta G* were calculated from the TG curves. Prepared spherical copper nanoparticles were characterized using UV-Vis spectroscopy and transition electron microscope (TEM). The spectral data showed the formation of surface complex between azo-dye ligands and colloidal copper nanopartides through (-OH) anchoring group. The stability constant of the prepared copper nanoparticles complexes is higher compared with the corresponding bulk ones due to the larger surface area of copper nanoparticles. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.07.019