| 207598-76-3

• CAS: 207598-76-3
• 化学式: C₅₄H₂₂Fe₂O₁₀Re₂S₃
• 分子量: 1411.07
• InChiKey: RXBOYFSPZNUMGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 在 钯 双(乙腈)氯化钯(II) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以23%的产率得到
  参考文献：
  名称：

  Combined Use of Palladium-Catalyzed Carbon−Carbon and Metal−Carbon Bond Formations for the Construction of Poly(metallaacetylide) Tethers

  摘要：

  The reaction between (eta(5)-C5H4I)Fe(CO)(2)CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron dimer CH3(CO)(2)Fe(eta(5)-C5H4)C=CC=CHSCH=CC=C(eta(5)-C5H4)Fe(CO)(2)CH3 (4), which upon treatment with I-2 is transformed to the corresponding diiodide I(CO)(2)Fe(eta(5)-C5H4)C=CC=CHSCH=CC=C(eta(5)-C5H4)Fe(CO)(2)I (5). Re action of the latter, in the presence of palladium, with the (trimethylstannyl) acetylide derivatives LnM(eta(5)-C5H4)C=CC=CHSCH=CC=CSn(CH3)(3) (9a, MLn = W(CO)(3)CH3, 9b, MLn = Re(CO)(3)) affords the polymetallaacetylide tethers LnM(eta(5)-C5H4)C=CC=CHSCH=CC=CFe-(CO)(2)(eta(5)-C5H4)C=CC=CHSCH=CC=C(eta(5)-C5H4)(CO)(2)FeC=CC=CHSCH=CC=C(eta(5)-C5H4)-MLn (10, MLn = W(CO)(3)CH3; 11, MLn = Re(CO)(3)). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.

  DOI：

  10.1021/om971094x