bis(1,10-phenanthroline-N,N')copper(II) tetrathionate | 207385-35-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: bis(1,10-phenanthroline-N,N')copper(II) tetrathionate
• CAS: 207385-35-1
• 化学式: C₂₄H₁₆CuN₄O₆S₄
• 分子量: 648.224
• InChiKey: JSCBCLLRTKWBQV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 copper(II) sulfate 、 sodium thiosulfate 以 甲醇 、 水 为溶剂， 生成 bis(1,10-phenanthroline-N,N')copper(II) tetrathionate
  参考文献：
  名称：

  Bis(1,10-phenanthroline-N,N')copper(II) Tetrathionate and Tris(1,10-phenanthroline-N,N')copper(II) Tetrathionate Pentahydrate

  摘要：

  The structures of [Cu(C12H8N2)(2)(S4O6)], (I), and [CU(C12H8N2)(3)](S4O6).5H(2)O, (II), are reported. Compound pound (I) consists of infinite polymeric chains where copper displays a typical (4+2) coordination and prepare S4O6 connects Cu(phen)(2) (phen is phenanthroline) units through rather long Cu...O contacts. Compound (II), instead, has a purely ionic character displaying [Cu(phen)(3)](2+) and S4O62- monomeric units. Equatorial and apical bonds in the copper coordination spheres have mean values of 2.003(5)/2.467(12) and 2.056 (3)/2.311(13)Angstrom for (I) and (II), respectively. Some short O...OW contacts in (II) suggest the existence of hydrogen bonding involving some of the water molecules of hydration.

  DOI：

  10.1107/s0108270197016284