[(Cu(NO3)2(methanol))2(2,7-bis(di-2-pyridylamino)naphthalene)] | 937726-38-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [(Cu(NO3)2(methanol))2(2,7-bis(di-2-pyridylamino)naphthalene)]
• CAS: 937726-38-0
• 化学式: C₃₂H₃₀Cu₂N₁₀O₁₄
• 分子量: 905.741
• InChiKey: UWWDGHJAZQBSEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 2,7-bis(di-2-pyridylamino)naphthalene 、 copper(II) nitrate 以 甲醇 为溶剂， 以52%的产率得到[(Cu(NO3)2(methanol))2(2,7-bis(di-2-pyridylamino)naphthalene)]
  参考文献：
  名称：

  Coordination chemistry of di-2-pyridylamine-based bridging heterocyclic ligands: A structural study of coordination polymers and discrete dinuclear complexes

  摘要：

  Four new bridging ligands containing two di-2-pyridylamine subunits have been synthesised. The coordination chemistry of these, along with one previously reported ligand, has been investigated through reactions with various silver(l), copper(II) and palladium(II) reactants. Typically, reaction of these ligands with silver(l) salts gave 1-D coordination polymers, within which the ligands act as divergent bridging units, while reaction with copper(II) and palladium(II) precursors provided discrete dinuclear complexes with chelating bidentate subunits. The complexes were characterised by a combination of elemental analysis, NMR spectroscopy and X-ray crystallography. The silver coordination polymers displayed interesting variations in supramolecular architecture, attributed to weak secondary interactions, such as Ag center dot center dot center dot pi-bonding. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.10.031