| 643746-57-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• CAS: 643746-57-0
• 化学式: C₄₈H₅₀N₆O₂Zn
• 分子量: 808.354
• InChiKey: WXDYKIDIJCGCBI-RYBHXQHESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 zinc diacetate 以 甲醇 、 氯仿 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  Porphyrin xanthene amides: anchoring distal H-bonding in heme models

  摘要：

  Distal H-bonding to axial ligand is strategically introduced in metalloporphyrin models by modifying porphyrin xanthene acid in which the carboxyl proton is preferentially H-bonded to the xanthene oxygen. Xanthene carboxamide is able to deliver intramolecular H-bonding and simultaneously lock into a well-defined conformation. Multipoint recognition of ligand is demonstrated in an amidinium-acetate-Zn porphyrin complex, mimicking a structural feature found in sulfite reductase.(C) 2003 Elsevier Science B.V. All rights reserved. Distal H-bonding to axial ligand is strategically introduced in metalloporphyrin models by modifying porphyrin xanthene acid in which the carboxyl proton is preferentially H-bonded to the xanthene oxygen. Xanthene carboxamide is able to deliver intramolecular H-bonding and simultaneously lock into a well-defined conformation. Multipoint recognition of ligand is demonstrated in an amidinium-acetate-Zn porphyrin complex, mimicking a structural feature found in sulfite reductase. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00118-x