1,5-naphthylenebis(amino-2-naphthylglyoxime) | 677736-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,5-naphthylenebis(amino-2-naphthylglyoxime)
• CAS: 677736-30-0
• 化学式: C₃₄H₂₆N₆O₄
• 分子量: 582.618
• InChiKey: QKWOSCSGDBQJHS-UHFFFAOYSA-N

物化性质

• 熔点：
  189 °C
• 沸点：
  909.5±75.0 °C(Predicted)
• 密度：
  1.37±0.1 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  nickel(II) chloride hexahydrate 、 1,5-naphthylenebis(amino-2-naphthylglyoxime) 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以87%的产率得到[Ni((C10H7C(NO)C(NOH)NH)2C10H6)]n
  参考文献：
  名称：

  The Synthesis of Four New bis(Amino‐2‐naphthylglyoximes) and Their Polymeric Complexes

  摘要：

  Four new bis(Amino-2-naphthylglyoxime) compounds, 1,4-phenylenebis (Amino-2-naphthylglyoxime) (LH2)-H-1, 1,5-naphthylenebis(amino-2-naphthylglyoxime) (LH2)-H-2, dimethylene-4,4'-bis(Amino-2-naphthylglyoxime) (LH2)-H-3, and diethylene-4,4-bis(Amino-2-naphthylelyoxime) (LH2)-H-4, have been synthesized from anti-2-naphthylglyoxime and the corresponding aromatic diamines. Their polymeric complexes with Ni(II), Co(II) and Cu(II) have been prepared. The Ni(II) and Cu(II) complexes of these ligands have been found to be square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. H-1 NMR, IR, magnetic susceptibility and elemental analytical data of the complexes and ligands are discussed.

  DOI：

  10.1081/sim-120023496