Mn(O2C(CH2)3CO2)(1,10-phenanthroline) | 210534-84-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: Mn(O2C(CH2)3CO2)(1,10-phenanthroline)
• 英文别名: manganese(2+);pentanedioate;1,10-phenanthroline
• CAS: 210534-84-2
• 化学式: C₅H₆O₄*C₁₂H₈N₂*Mn
• 分子量: 365.247
• InChiKey: YCHGGZSOMILTHV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.44
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 manganese(II) glutarate tetrahydrate 以 乙醇 为溶剂， 以94%的产率得到Mn(O2C(CH2)3CO2)(1,10-phenanthroline)
  参考文献：
  名称：

  Synthesis and catalytic activity of manganese(II) complexes of pentanedioic acid; X-ray crystal structure of [Mn(phen)2(H2O)2][Mn(O2C(CH2)3CO2)(phen)2H2O]-(O2C(CH2)3CO2) · 12H2O (phen = 1,10-phenanthroline)

  摘要：

  Reaction of manganese(II) acetate tetrahydrate with pentanedioic acid gives [Mn(O2C(CH2)(3)CO2)]. H2O (1). Complex 1 reacts with 1,10-phenanthroline (phen) (similar to 1:3 mol ratio) in ethanol giving the mono-phenanthroline complex [Mn(O2C(CH2)(3)CO2) (phen)] (2). Using less phenanthroline (similar to 1 mol of 1:2 mol phenanthroline) in an ethanol-water solvent mixture gives the bis-phenanthroline complex [Mn(phen)(2)(H2O)(2)] [Mn(O2C(CH2)(3)CO2) (phen)(2)H2O] (O2C(CH2)(3)CO2). 12H(2)O (3) which was characterised using X-ray crystallography. Complex 3 contains two independent mononuclear manganese(II) species, the dication [Mn(phen)(2)(H2O)(2)](2+) and the neutral manganese pentanedioate complex [Mn(O2C(CH2)(3)CO2) (phen)(2)(H2O)], along with a non-coordinated (O2C(CH2)(3)CO2)(2-) counter dianion. In the dication [Mn(phen)(2)(H2O)(2)](2+) the manganese atom is coordinated to four nitrogen atoms from two chelating phenanthroline ligands and two oxygen atoms from two cisoid water molecules. In the neutral fragment [Mn(O2C(CH2)(3)CO2) (phen)(2)(H2O)] the metal atom is coordinated to four nitrogen atoms from two chelating phenanthroline ligands, one oxygen atom from a unidentate (O2C(CH2)(3)CO2)(2-) ligand and one oxygen atom from a water molecule which is cis with respect to the coordinated carboxylate oxygen of the pentanedioate ligand. IR, magnetic and conductivity data for the complexes are given. All three complexes are catalysts for the disproportionation of H2O2 in the presence of added imidazole. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)06160-4
• 作为试剂：
  描述：

  双氧水 在 Mn(O2C(CH2)3CO2)(1,10-phenanthroline) imidazole 作用下， 以 not given 为溶剂， 生成 水 、 氧气
  参考文献：
  名称：

  Synthesis and catalytic activity of manganese(II) complexes of pentanedioic acid; X-ray crystal structure of [Mn(phen)2(H2O)2][Mn(O2C(CH2)3CO2)(phen)2H2O]-(O2C(CH2)3CO2) · 12H2O (phen = 1,10-phenanthroline)

  摘要：

  Reaction of manganese(II) acetate tetrahydrate with pentanedioic acid gives [Mn(O2C(CH2)(3)CO2)]. H2O (1). Complex 1 reacts with 1,10-phenanthroline (phen) (similar to 1:3 mol ratio) in ethanol giving the mono-phenanthroline complex [Mn(O2C(CH2)(3)CO2) (phen)] (2). Using less phenanthroline (similar to 1 mol of 1:2 mol phenanthroline) in an ethanol-water solvent mixture gives the bis-phenanthroline complex [Mn(phen)(2)(H2O)(2)] [Mn(O2C(CH2)(3)CO2) (phen)(2)H2O] (O2C(CH2)(3)CO2). 12H(2)O (3) which was characterised using X-ray crystallography. Complex 3 contains two independent mononuclear manganese(II) species, the dication [Mn(phen)(2)(H2O)(2)](2+) and the neutral manganese pentanedioate complex [Mn(O2C(CH2)(3)CO2) (phen)(2)(H2O)], along with a non-coordinated (O2C(CH2)(3)CO2)(2-) counter dianion. In the dication [Mn(phen)(2)(H2O)(2)](2+) the manganese atom is coordinated to four nitrogen atoms from two chelating phenanthroline ligands and two oxygen atoms from two cisoid water molecules. In the neutral fragment [Mn(O2C(CH2)(3)CO2) (phen)(2)(H2O)] the metal atom is coordinated to four nitrogen atoms from two chelating phenanthroline ligands, one oxygen atom from a unidentate (O2C(CH2)(3)CO2)(2-) ligand and one oxygen atom from a water molecule which is cis with respect to the coordinated carboxylate oxygen of the pentanedioate ligand. IR, magnetic and conductivity data for the complexes are given. All three complexes are catalysts for the disproportionation of H2O2 in the presence of added imidazole. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)06160-4

文献信息

• Two Glutarato Bridged Coordination Polymers: ${_{\infty}^1}${[Mn(phen)]2L4/2} and ${_{\infty}^1}${[Zn(phen)(H2O)]L2/2}·H2O with H2L = Glutaric Acid
  作者：Yue-Qing Zheng、Wen-Han Liu、Jian-Li Lin

  DOI：10.1002/1521-3749(200205)628:4<824::aid-zaac824>3.0.co;2-u

  日期：2002.5

  Koordinationspolymere [Mn(phen)]2(C5H6O4)4/2} (1) und [Zn(phen)(H2O)](C5H6O4)2/2}· H2O (2) wurden strukturell charakterisiert mit rontgnographischen Methoden. Einkristalldaten: (1) P2/c (Nr. 13), a = 10, 340(2)A, b = 10, 525(2)A, c = 13, 891(2)A, β = 98, 31(1)°, U = 1495, 9(5)A3, Z = 2; (2) P21/n (Nr. 14), a = 6, 738(1)A, b = 25, 636(3)A, c = 10, 374(1)A, β = 106, 13(1)°, U = 1721, 4(4)A3, Z = 4. Der Komplexe 1 besteht

  对两种新型戊二酸桥连配位聚合物[Mn(phen)]2(C5H6O4)4/2}(1)和[Zn(phen)(H2O)]( )2/2}· (2)进行结构表征基于单晶 X 射线衍射数据。晶体数据：（1）P2/c（no.13），a=10.340（2）A，b=10.525（2）A，c=13.891（2）A，β=98.31（1）°，U=1495.9 (5) A3, Z = 2; (2) P21/n (no.14), a = 6.738 (1) A, b = 25.636 (3) A, c = 10.374 (1) A, β = 106.13 (1)°, U = 1721.4 (4) A3, Z = 4. 复合物 1 由一维带状 [Mn (phen)] 2 ( ) 4/2} 链组成，其中 [Mn (phen)] 单元通过戊二酸配体相互连接以生成 8-和 16 元环。Mn 原子由一个