9-hydroxyphenanthren-10-yl 2-(3,3,3-trifluoro-2-hydroxy-1-oxo-2-trifluoromethylpropyl)phenyl phenylphosphonate | 1350611-11-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 9-hydroxyphenanthren-10-yl 2-(3,3,3-trifluoro-2-hydroxy-1-oxo-2-trifluoromethylpropyl)phenyl phenylphosphonate
• CAS: 1350611-11-8
• 化学式: C₃₀H₁₉F₆O₆P
• 分子量: 620.441
• InChiKey: HCIPMXFYNWMTRO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-phenyl-4,4-bis(trifluoromethyl)-4,5-dihydrospiro[[1,3,2]benzodioxaphosphepine-2,2'-phenanthro[9,10-d][1,3,2]dioxaphosphol]-5-one 在 水 作用下， 以 氘代氯仿 为溶剂， 生成 9-hydroxyphenanthren-10-yl 2-(3,3,3-trifluoro-2-hydroxy-1-oxo-2-trifluoromethylpropyl)phenyl phenylphosphonate
  参考文献：
  名称：

  Reactions of 2-phenyl-4,4-bis(trifluoromethyl)-4,5-dihydro-1,3,2-benzodioxaphosphepin-5-one with phenanthrenequinone and dibenzoyl

  摘要：

  Reactions of 2-phenyl-4,4-bis(trifluoromethyl)-4,5-dihydro-1,3,2-benzodioxaphosphepin-5-one with 9,10-phenanthrenequinone and dibenzoyl gave hydrolytically unstable spirophosphoranes with five- and seven-membered rings, 2-phenyl-4,4-bis(trifluoromethyl)-4,5-dihydrospiro[[1,3,2]benzodioxaphosphepine-2,2'-phenanthro[9,10-d][1,3,2]dioxaphosphol]-5-one and 2,4',5'-triphenyl-4,4-bis(trifluoromethyl)-4,5-dihydrospiro[[1,3,2]benzodioxaphosphepine-2,2'-[1,3,2]dioxaphosphol]-5-one. The structure of the first of these was proved by X-ray analysis.

  DOI：

  10.1134/s1070428011100125